A Regenerative Coking-resistant CO<sub>2</sub> Hydrogenation Reactor using a Protonic Ceramic Electrolysis Cell with Thin and Robust Fuel Electrode

doi:10.1002/aenm.202402208

	A Regenerative Coking-resistant CO₂ Hydrogenation Reactor using a Protonic Ceramic Electrolysis Cell with Thin and Robust Fuel Electrode
	Miao, Xiaoyun 1,2; Feng, Jiangyuan 3; Dai, Zhongqin1,4 ; Zhu, Xingzhi 1,2; Wen, Jianjun 1; Zhang, Liang 3,5; Ye, Xiaofeng 1,2; Zhou, Yucun 3; Wen, Zhaoyin 1,2
	2024-07-01
发表期刊	ADVANCED ENERGY MATERIALS (IF:24.4[JCR-2023],27.2[5-Year])
ISSN	1614-6832
EISSN	1614-6840
卷号	14 期号:42
发表状态	已发表
DOI	10.1002/aenm.202402208
摘要	A CO2 hydrogenation reactor based on protonic ceramic electrolysis cells (PCECs) is one of the most promising options for the efficient and clean conversion of CO2. However, insufficient performance and durability have hindered the practical application of such CO2 hydrogenation reactors. Here, fabricates a large-area (approximate to 10 cm(2)) tubular air electrode supported PCEC (AES-PCEC) and develop a fuel electrode regeneration strategy for efficient and durable CO2 hydrogenation. The AES-PCEC demonstrates a CO yield of 2.88 mL min(-1) at 650 degrees C while maintaining excellent durability for over 1100 h. The high stability of the AES-PCEC can be attributed to the robust and thin fuel electrode structure as well as the water-mediated carbon removal regeneration mechanism. Density functional theory calculations have confirmed the regeneration mechanism facilitated by the excellent water hydration and dissociation capability of the BaCe0.4Zr0.4Y0.1Yb0.1O3-sigma. This work offers a feasible strategy to design high-performance and durable PCEC-based CO2 hydrogenation reactors.
关键词	carbon removal CO2 hydrogenation large-area tubular cells protonic ceramic electrolysis cells (PCECs) thin fuel electrode
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收录类别	SCI ; EI
语种	英语
资助项目	National Natural Science Foundation of China[52372246] ; National Key R&D Program of China[2021YFB4001400] ; Shanghai Engineering Research Center of Inorganic Energy Materials and Electric Power Sources[18DZ2280800]
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science ; Physics
WOS类目	Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:001280564500001
出版者	WILEY-V C H VERLAG GMBH
EI入藏号	20243116796825
EI主题词	Carbon dioxide
EI分类号	702.2 Fuel Cells ; 801.4.1 Electrochemistry ; 802.2 Chemical Reactions ; 804 Chemical Products Generally ; 804.2 Inorganic Compounds ; 922.1 Probability Theory ; 931.3 Atomic and Molecular Physics ; 931.4 Quantum Theory ; Quantum Mechanics
原始文献类型	Article in Press
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/408295
专题	物质科学与技术学院物质科学与技术学院_博士生
通讯作者	Ye, Xiaofeng; Zhou, Yucun; Wen, Zhaoyin
作者单位	1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine M, Shanghai 200050, Peoples R China 2.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 3.Beijing Huairou Lab, Beijing 101400, Peoples R China 4.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 5.Tsinghua Univ, Sch Vehicle & Mobil, Beijing 100084, Peoples R China
推荐引用方式 GB/T 7714	Miao, Xiaoyun,Feng, Jiangyuan,Dai, Zhongqin,et al. A Regenerative Coking-resistant CO₂ Hydrogenation Reactor using a Protonic Ceramic Electrolysis Cell with Thin and Robust Fuel Electrode[J]. ADVANCED ENERGY MATERIALS,2024,14(42).
APA	Miao, Xiaoyun.,Feng, Jiangyuan.,Dai, Zhongqin.,Zhu, Xingzhi.,Wen, Jianjun.,...&Wen, Zhaoyin.(2024).A Regenerative Coking-resistant CO₂ Hydrogenation Reactor using a Protonic Ceramic Electrolysis Cell with Thin and Robust Fuel Electrode.ADVANCED ENERGY MATERIALS,14(42).
MLA	Miao, Xiaoyun,et al."A Regenerative Coking-resistant CO₂ Hydrogenation Reactor using a Protonic Ceramic Electrolysis Cell with Thin and Robust Fuel Electrode".ADVANCED ENERGY MATERIALS 14.42(2024).