Selective catalytic reduction of NOx with methane over cobalt-exchanged SSZ-39 zeolite
2024-07-11
发表期刊CHEMICAL ENGINEERING JOURNAL (IF:13.3[JCR-2023],13.2[5-Year])
ISSN1385-8947
EISSN1873-3212
卷号496
发表状态已发表
DOI10.1016/j.cej.2024.153191
摘要

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) with methane has been considered as an efficient technology for simultaneous removal of emitted NOx and unburned CH4 in both transport (heavy-duty vehicles and ships) and power plant sectors, where the development of efficient catalysts is critical for the commercialization of CH4-SCR technology. In this manuscript, it is shown that Co-SSZ-39 (Co-AEI) is highly efficient for the CH4-SCR. Characterizations of the catalysts reveal that divalent cobalt ions (Co2+) located at the exchange position are active species for this CH4-SCR. In particular, the Co-SSZ-39 exhibited high hydrothermal stability and excellent tolerances to water, CO, and SO2, which offer a good opportunity for potential applications of the Co-SSZ-39 for CH4-SCR in the future.

关键词CH4-SCR Co-SSZ-39 zeolite CH4 Hydrothermal stability CO and SO2 tolerance
学科领域催化化学
学科门类工学::材料科学与工程(可授工学、理学学位)
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收录类别SCI ; EI
语种英语
资助项目Program of China[2023YFC3707201] ; National Natural Science Foun-dation of China["22125204","U20B6004","22288101"] ; Key Research and Development Program of Zhejiang Province[2021C01080]
WOS研究方向Engineering
WOS类目Engineering, Environmental ; Engineering, Chemical
WOS记录号WOS:001281039300001
出版者Elsevier B.V.
EI入藏号20243016759587
EI主题词Zeolites
EI分类号451.2 Air Pollution Control ; 549.3 Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals ; 803 Chemical Agents and Basic Industrial Chemicals ; 804 Chemical Products Generally ; 804.1 Organic Compounds ; 804.2 Inorganic Compounds
原始文献类型Journal article (JA)
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/401454
专题物质科学与技术学院_博士生
物质科学与技术学院_PI研究组_马延航组
物质科学与技术学院_PI研究组_杨帆组
共同第一作者Lunjia Zhang
通讯作者Xiangju Meng; Fan Yang; Feng-Shou Xiao
作者单位
1.Department of Chemistry, Zhejiang University, Hangzhou 310058, PR China
2.School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, PR China
3.Key Lab of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, PR China
4.Kente Catalysts Inc., Taizhou, 317306, PR China
5.College of Chemistry, Jilin University, Changchun 130021, PR China
通讯作者单位物质科学与技术学院
推荐引用方式
GB/T 7714
Jian Li,Lunjia Zhang,Ye Ma,et al. Selective catalytic reduction of NOx with methane over cobalt-exchanged SSZ-39 zeolite[J]. CHEMICAL ENGINEERING JOURNAL,2024,496.
APA Jian Li.,Lunjia Zhang.,Ye Ma.,Kai Fan.,Juan Zhang.,...&Feng-Shou Xiao.(2024).Selective catalytic reduction of NOx with methane over cobalt-exchanged SSZ-39 zeolite.CHEMICAL ENGINEERING JOURNAL,496.
MLA Jian Li,et al."Selective catalytic reduction of NOx with methane over cobalt-exchanged SSZ-39 zeolite".CHEMICAL ENGINEERING JOURNAL 496(2024).
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