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Hydrothermal synthesis and morphology control mechanism of BaTiO3 from NaTi3O6(OH)(H2O)2 precursors
2024
发表期刊CERAMICS INTERNATIONAL (IF:5.1[JCR-2023],4.7[5-Year])
ISSN0272-8842
EISSN1873-3956
卷号50期号:12页码:21779-21787
发表状态已发表
DOI10.1016/j.ceramint.2024.03.290
摘要

We present a study on the hydrothermal synthesis of BaTiO3 utilizing NaTi3O6(OH)- (H2O)2 nanowires, which was conducted by controlling temperature, alkalinity and time. Initially, increased temperature has promoted the synthesis of BaTiO3 and induce a change in the morphology. When the temperature increases within the range of 90 °C–210 °C, the morphology of the product transitions from nanoparticle to spindle-shaped to nanowires. Then, a time-dependent experiment was conducted to investigate the mechanisms involved in the transformation of the morphology. The formation of nanoparticle occurs through the process of dissolution-crystallization, while the formation of BaTiO3 nanowires is attributed to hydrothermal ion exchange. Also, the hydrothermal process is characterized by grain aggregation and grain growth. By investigating the synthesis and morphology evolution of BaTiO3, this work holds significant potential for the synthesis of BaTiO3 nanowires or other perovskite-type MTiO3 employing titanate as a precursor. © 2024 Elsevier Ltd and Techna Group S.r.l.

关键词Barium titanate Grain growth Hydrothermal synthesis Morphology Nanoparticles Nanowires Perovskite Sodium compounds Control mechanism Dissolution-crystallization Hydrothermal ion exchange Hydrothermal process Increased temperature Morphology control Morphology evolution Synthesis control Temperature increase Time dependent
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收录类别EI ; SCI
语种英语
资助项目National Natural Science Foundation of China["U2002217","11774366"] ; Key Deployment Projects of Chinese Academy of Sciences[2021-3- 3]
WOS研究方向Materials Science
WOS类目Materials Science, Ceramics
WOS记录号WOS:001238516900001
出版者Elsevier Ltd
EI入藏号20241415842001
EI主题词Ion exchange
EI分类号482.2 Minerals ; 761 Nanotechnology ; 802.2 Chemical Reactions ; 804.2 Inorganic Compounds ; 812.1 Ceramics ; 931.2 Physical Properties of Gases, Liquids and Solids ; 933 Solid State Physics ; 933.1.2 Crystal Growth ; 951 Materials Science
原始文献类型Article in Press
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/359872
专题物质科学与技术学院
物质科学与技术学院_特聘教授组_许钫钫组
物质科学与技术学院_硕士生
物质科学与技术学院_博士生
通讯作者Chen, Xuefeng; Wang, Genshui
作者单位
1.Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 201800, China;
2.School of Physical Science and Technology, ShanghaiTech University, Shanghai; 201210, China;
3.Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou; 341119, China;
4.State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China
第一作者单位物质科学与技术学院
推荐引用方式
GB/T 7714
Chen, Shuai,Han, Bing,Chen, Xuefeng,et al. Hydrothermal synthesis and morphology control mechanism of BaTiO3 from NaTi3O6(OH)(H2O)2 precursors[J]. CERAMICS INTERNATIONAL,2024,50(12):21779-21787.
APA Chen, Shuai,Han, Bing,Chen, Xuefeng,Xu, Fangfang,&Wang, Genshui.(2024).Hydrothermal synthesis and morphology control mechanism of BaTiO3 from NaTi3O6(OH)(H2O)2 precursors.CERAMICS INTERNATIONAL,50(12),21779-21787.
MLA Chen, Shuai,et al."Hydrothermal synthesis and morphology control mechanism of BaTiO3 from NaTi3O6(OH)(H2O)2 precursors".CERAMICS INTERNATIONAL 50.12(2024):21779-21787.
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