上海科技大学知识管理系统

Multivariate metal–organic frameworks (MTV-MOFs) provide a handle over programming MOF's physicochemical properties for use in functional applications. In this review, the state-of-art design features of MTV-MOFs are summarized, including multivariate functionalities, mixed metals, and post-synthetic modification, and highlight their resulting fine-tuned performance in practical applications, such as gas storage, gas separation, water harvesting, luminescence sensing, heterogeneous catalysis, and drug delivery. Furthermore, a vision is provided for future research avenues, in which MTV-MOFs enable the incorporation of a variety of functionalities, metals, linkers, secondary building units (SBUs), and pore metrics along a specific crystallographic direction with respect to the ordered backbone. Future directions focus on mechanistic and kinetics investigations into the formation of MTV-MOFs in addition to high-throughput screening with the aim of automation and artificial intelligence. © 2024 Wiley-VCH GmbH.