Modulation of Electronic Metal-Support Interaction between Cu and ZnO by Er for Effective Low-Temperature CO2 Hydrogenation to Methanol

doi:10.1021/acscatal.3c04608

KMS > 2060研究院

	Modulation of Electronic Metal-Support Interaction between Cu and ZnO by Er for Effective Low-Temperature CO2 Hydrogenation to Methanol
	Huang, Chaojie 1,2; Zhang, Shunan3 ; Wang, Wenbo 5; Zhou, Haozhi3 ; Shao, Zilong 1,2; Xia, Lin 1; Wang, Hui1,3 ; Sun, Yuhan1,3,4
	2024-02-02
发表期刊	ACS CATALYSIS (IF:11.3[JCR-2023],12.6[5-Year])
ISSN	2155-5435
EISSN	2155-5435
卷号	14 期号:3 页码:1324-1335
发表状态	已发表
DOI	10.1021/acscatal.3c04608
摘要	Methanol produced by CO2 hydrogenation is an essential carrier for a sustainable carbon cycle. However, achieving an efficient methanol synthesis on traditional CuZnO catalysts at low temperatures remains challenging due to the inertness of CO2. Herein, we designed Er-CuZnO catalysts that exhibited remarkable activity for low-temperature methanol synthesis. At 170 °C, the catalyst achieved a methanol selectivity of 89.8% at a CO2 conversion of 8.5% on Er0.2CuZnO, which outperformed most CuZnO-based catalysts. The particle size of ZnO was reduced after Er was added to the lattice, which increased the Cu-ZnO interfaces and created a strong electronic metal-support interaction (EMSI) between Cu and ZnO. The electron was transferred from ZnO to Cu, forming Cuδ−. Cuδ− with more negative charges enhanced CO2 adsorbed species and intermediates activation, while facilitating surface carbonate activation and the hydrogenation of CO intermediates into HCO species, promoting the methanol formation at low temperatures. © 2024 American Chemical Society
关键词	Carbon dioxide Catalyst activity Catalyst selectivity Copper Hydrogenation II-VI semiconductors Methanol Particle size Synthesis gas manufacture Temperature Zinc oxide Carbon cycles Electronic metal-support interaction Er+ doping Low-temperature methanol synthesis Lows-temperatures Metal-support interactions Methanol selectivity Methanol synthesis Particles sizes ]+ catalyst
收录类别	EI
语种	英语
出版者	American Chemical Society
EI入藏号	20240315398783
EI主题词	Chemical activation
EI分类号	544.1 Copper ; 641.1 Thermodynamics ; 712.1 Semiconducting Materials ; 802.2 Chemical Reactions ; 803 Chemical Agents and Basic Industrial Chemicals ; 804 Chemical Products Generally ; 804.1 Organic Compounds ; 804.2 Inorganic Compounds
原始文献类型	Journal article (JA)
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/349723
专题	2060研究院物质科学与技术学院_特聘教授组_孙予罕组物质科学与技术学院_博士生 2060研究院_公共科研平台_低碳转化利用系统研究组
通讯作者	Wang, Hui
作者单位	1.CAS Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai; 201210, China 2.University of the Chinese Academy of Sciences, Beijing; 100049, China 3.Institute of Carbon Neutrality, Shanghai Tech University, Shanghai; 201203, China 4.Shanghai Institute of Cleantech Innovation, Shanghai; 201620, China 5.CNOOC Institute of Chemical & Advanced Materials (Beijing) Co. Ltd., Beijing; 102209, China
通讯作者单位	上海科技大学
推荐引用方式 GB/T 7714	Huang, Chaojie,Zhang, Shunan,Wang, Wenbo,et al. Modulation of Electronic Metal-Support Interaction between Cu and ZnO by Er for Effective Low-Temperature CO2 Hydrogenation to Methanol[J]. ACS CATALYSIS,2024,14(3):1324-1335.
APA	Huang, Chaojie.,Zhang, Shunan.,Wang, Wenbo.,Zhou, Haozhi.,Shao, Zilong.,...&Sun, Yuhan.(2024).Modulation of Electronic Metal-Support Interaction between Cu and ZnO by Er for Effective Low-Temperature CO2 Hydrogenation to Methanol.ACS CATALYSIS,14(3),1324-1335.
MLA	Huang, Chaojie,et al."Modulation of Electronic Metal-Support Interaction between Cu and ZnO by Er for Effective Low-Temperature CO2 Hydrogenation to Methanol".ACS CATALYSIS 14.3(2024):1324-1335.