Azodicarboxylate as a comonomer for radical polymerization to incorporate nitrogen–nitrogen single bonds into the polymer chain

doi:10.1002/pol.20230672

	Azodicarboxylate as a comonomer for radical polymerization to incorporate nitrogen–nitrogen single bonds into the polymer chain
	Shi, Qingdan; An, Bang; Li, Yifan
	2023
发表期刊	JOURNAL OF POLYMER SCIENCE (IF:3.9[JCR-2023],3.7[5-Year])
ISSN	2642-4150
EISSN	2642-4169
卷号	62 期号:6 页码:1028-1033
发表状态	已发表
DOI	10.1002/pol.20230672
摘要	In organic synthesis, azodicarboxylates are frequently used as an aza-dienophile and electrophilic amination agent. To create carbon–nitrogen bonds, azodicarboxylates typically react with nucleophiles or radicals. This report explores its reactivity as a co-monomer towards radical polymerization to introduce nitrogen–nitrogen single bonds into the polymer chain. Azodicarboxylates are capable of copolymerizing with styrenic monomers to achieve linear polymers with 40% feed. © 2023 Wiley Periodicals LLC.
关键词	Amination Amines Atom transfer radical polymerization Monomers Azodicarboxylates Carbon nitrogen bonds Comonomers Dienophiles Electrophilic amination Organic synthesis Polymer chain containing hydrazine Polymer chains Single bond Styrenic monomers
收录类别	EI
语种	英语
出版者	John Wiley and Sons Inc
EI入藏号	20234715094865
EI主题词	Nitrogen
EI分类号	802.2 Chemical Reactions ; 804 Chemical Products Generally ; 804.1 Organic Compounds ; 815.2 Polymerization
原始文献类型	Article in Press
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/347902
专题	物质科学与技术学院物质科学与技术学院_硕士生物质科学与技术学院_博士生物质科学与技术学院_PI研究组_李一凡组
共同第一作者	An, Bang
通讯作者	Li, Yifan
作者单位	School of Physical Science and Technology, ShanghaiTech University, Shanghai, China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Shi, Qingdan,An, Bang,Li, Yifan. Azodicarboxylate as a comonomer for radical polymerization to incorporate nitrogen–nitrogen single bonds into the polymer chain[J]. JOURNAL OF POLYMER SCIENCE,2023,62(6):1028-1033.
APA	Shi, Qingdan,An, Bang,&Li, Yifan.(2023).Azodicarboxylate as a comonomer for radical polymerization to incorporate nitrogen–nitrogen single bonds into the polymer chain.JOURNAL OF POLYMER SCIENCE,62(6),1028-1033.
MLA	Shi, Qingdan,et al."Azodicarboxylate as a comonomer for radical polymerization to incorporate nitrogen–nitrogen single bonds into the polymer chain".JOURNAL OF POLYMER SCIENCE 62.6(2023):1028-1033.