ShanghaiTech University Knowledge Management System
| Ampere-Level CO2-to-Ethanol Conversion via Boron-Incorporated Copper Electrodes | |
| 2023-11-10 | |
| 发表期刊 | ACS ENERGY LETTERS (IF:19.3[JCR-2023],20.8[5-Year]) |
| ISSN | 2380-8195 |
| EISSN | 2380-8195 |
| 卷号 | 8期号:11页码:4867-4874 |
| 发表状态 | 已发表 |
| DOI | 10.1021/acsenergylett.3c01901 |
| 摘要 | Partial positive valence Cu (Cuδ+) sites on Cu-based electrocatalysts are important for C-C coupling to form C2+ products; however, maintaining the stability of Cuδ+ remains a challenge. Herein, an ultrastable Cuδ+ (0 2+ Faradaic efficiency (FE) of 78.9% at −0.91 V (vs reversible hydrogen electrode), of which the ethanol FE reaches 52.4% with an ultrahigh partial current density of 1.25 A cm-2, far outperforming state-of-the-art electrocatalysts, corresponding to the ethanol cathodic energy efficiency (CEE) of 27.7%. Spectroscopy and computation results show that introducing boron to optimize the coordination numbers and oxidation states of surface Cu atoms enables enrichment of locally asymmetric *COatop and *CHO intermediates to trigger asymmetric C-C coupling to form ethanol. © 2023 American Chemical Society. |
| 关键词 | Conversion efficiency Copper Copper compounds Electrocatalysts Electrodes Energy efficiency Ethanol Adsorption strength C-C coupling Co-adsorption Copper electrodes Cu-based Ethanol conversion Faradaic efficiencies Partial currents Reversible hydrogen electrodes Stability of Cu |
| 收录类别 | EI |
| 语种 | 英语 |
| 出版者 | American Chemical Society |
| EI入藏号 | 20234815126459 |
| EI主题词 | Boron |
| EI分类号 | 525.2 Energy Conservation ; 525.5 Energy Conversion Issues ; 544.1 Copper ; 549.3 Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals ; 803 Chemical Agents and Basic Industrial Chemicals ; 804.1 Organic Compounds |
| 原始文献类型 | Journal article (JA) |
| 引用统计 | 正在获取...
|
| 文献类型 | 期刊论文 |
| 条目标识符 | https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/347890 |
| 专题 | 物质科学与技术学院 物质科学与技术学院_特聘教授组_魏伟组 物质科学与技术学院_博士生 |
| 通讯作者 | Wei, Wei; Chen, Wei |
| 作者单位 | 1.Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai; 201210, China; 2.University of Chinese Academy of Sciences, Beijing; 100049, China; 3.School of Physical Science and Technology, ShanghaiTech University, Shanghai; 201203, China; 4.Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai; 201204, China |
| 通讯作者单位 | 物质科学与技术学院 |
| 推荐引用方式 GB/T 7714 | Wu, Gangfeng,Zhu, Chang,Mao, Jianing,et al. Ampere-Level CO2-to-Ethanol Conversion via Boron-Incorporated Copper Electrodes[J]. ACS ENERGY LETTERS,2023,8(11):4867-4874. |
| APA | Wu, Gangfeng.,Zhu, Chang.,Mao, Jianing.,Li, Guihua.,Li, Shoujie.,...&Chen, Wei.(2023).Ampere-Level CO2-to-Ethanol Conversion via Boron-Incorporated Copper Electrodes.ACS ENERGY LETTERS,8(11),4867-4874. |
| MLA | Wu, Gangfeng,et al."Ampere-Level CO2-to-Ethanol Conversion via Boron-Incorporated Copper Electrodes".ACS ENERGY LETTERS 8.11(2023):4867-4874. |
| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
修改评论
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。