Selective oxidation of aniline over a {Ce-3}-sandwiching POM catalyst in water

doi:10.1016/j.inoche.2023.110912

	Selective oxidation of aniline over a {Ce-3}-sandwiching POM catalyst in water
	Cai, Sheng 1,2; Kong, Xiang-Yu1,3 ; Wu, Xiao-Yuan 1; Wu, Weiming 1; Wang, Sa-Sa 1; Lu, Can-Zhong1,2,3,4
	2023-08-01
发表期刊	INORGANIC CHEMISTRY COMMUNICATIONS (IF:4.4[JCR-2023],3.6[5-Year])
ISSN	1387-7003
EISSN	1879-0259
卷号	154
发表状态	已发表
DOI	10.1016/j.inoche.2023.110912
摘要	The selective oxidation of aniline towards high value-added products in water is of great importance from both the elimination of aniline pollutant in water and the production of high value-added chemicals points of view. Herein, we report the synthesis and application of a {Ce-3}-sandwiching germanotungstate K10Na4[Ce3(mu(2)-O)(3)(GeW9O34)2]center dot 24H(2)O (1) in the selective oxidation of aniline and derivatives towards corresponding nitroso compounds in water with diluent H2O2 as the oxidant. Compound 1 has been carefully characterized by X-ray single-crystal diffraction, TG, FT-IR, PXRD, XPS, and SEM. Under optimized condition, aniline can be quantitatively converted and the selectivity towards nitrosobenzene reaches up to 86.0% without any additives. The performance comparisons of different catalysts reveal that the structural combination of oxo-cerium and oxotungsten facilitates the enhancement of catalytic performance.
关键词	Selective oxidation of aniline Nitrosobenzene Ce-sandwiching polyoxometalate Green process
URL	查看原文
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:001026713000001
出版者	ELSEVIER
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/321465
专题	物质科学与技术学院物质科学与技术学院_特聘教授组_卢灿忠组物质科学与技术学院_硕士生
通讯作者	Wang, Sa-Sa; Lu, Can-Zhong
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China 2.Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350117, Fujian, Peoples R China 3.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 4.Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
通讯作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Cai, Sheng,Kong, Xiang-Yu,Wu, Xiao-Yuan,et al. Selective oxidation of aniline over a {Ce-3}-sandwiching POM catalyst in water[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2023,154.
APA	Cai, Sheng,Kong, Xiang-Yu,Wu, Xiao-Yuan,Wu, Weiming,Wang, Sa-Sa,&Lu, Can-Zhong.(2023).Selective oxidation of aniline over a {Ce-3}-sandwiching POM catalyst in water.INORGANIC CHEMISTRY COMMUNICATIONS,154.
MLA	Cai, Sheng,et al."Selective oxidation of aniline over a {Ce-3}-sandwiching POM catalyst in water".INORGANIC CHEMISTRY COMMUNICATIONS 154(2023).