Coherent hexagonal platinum skin on nickel nanocrystals for enhanced hydrogen evolution activity

doi:10.1038/s41467-023-38018-2

	Coherent hexagonal platinum skin on nickel nanocrystals for enhanced hydrogen evolution activity
	Liu, Kai 1; Yang, Hao 2; Jiang, Yilan3,4 ; Liu, Zhaojun 1; Zhang, Shumeng 1; Zhang, Zhixue 1; Qiao, Zhun 1; Lu, Yiming 2; Cheng, Tao 2; Terasaki, Osamu3,4 ; Zhang, Qing3,4 ; Gao, Chuanbo 1
	2023-04-27
发表期刊	NATURE COMMUNICATIONS (IF:14.7[JCR-2023],16.1[5-Year])
EISSN	2041-1723
卷号	14 期号:1
发表状态	已发表
DOI	10.1038/s41467-023-38018-2
摘要	["Metastable noble metal nanocrystals may exhibit distinctive catalytic properties to address the sluggish kinetics of many important processes, including the hydrogen evolution reaction under alkaline conditions for water-electrolysis hydrogen production. However, the exploration of metastable noble metal nanocrystals is still in its infancy and suffers from a lack of sufficient synthesis and electronic engineering strategies to fully stimulate their potential in catalysis. In this paper, we report a synthesis of metastable hexagonal Pt nanostructures by coherent growth on 3d transition metal nanocrystals such as Ni without involving galvanic replacement reaction, which expands the frontier of the phase-replication synthesis. Unlike noble metal substrates, the 3d transition metal substrate owns more crystal phases and lower cost and endows the hexagonal Pt skin with substantial compressive strains and programmable charge density, making the electronic properties particularly preferred for the alkaline hydrogen evolution reaction. The energy barriers are greatly reduced, pushing the activity to 133 mA cm(geo)(-2) and 17.4 mA mu g(Pt)(-1) at -70 mV with 1.5 mu g of Pt in 1 M KOH. Our strategy paves the way for metastable noble metal catalysts with tailored electronic properties for highly efficient and cost-effective energy conversion.","Synthesis and modulation of metastable noble metal nanocrystal catalysts is interesting yet challenging. Here the authors report synthesis of metastable hexagonal Pt skins on Ni nanocrystals with modulated electronic structures and enhanced hydrogen evolution activities."]
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收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China["21903058","22173066","22071191","21671156"] ; Key Scientific and Technological Innovation Team of Shaanxi Province[2020TD-001] ; Collaborative Innovation Center of Suzhou Nano Science Technology[2019TQ0249] ; Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)[2022JQ-100] ; Shanghai Key Laboratory of HREM[SBK20190810] ; null[EM-02161943] ; null[21DZ2260400]
WOS研究方向	Science & Technology - Other Topics
WOS类目	Multidisciplinary Sciences
WOS记录号	WOS:000989625000027
出版者	NATURE PORTFOLIO
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/316406
专题	物质科学与技术学院_公共科研平台_物质科学电镜平台物质科学与技术学院_PI研究组_Osamu Terasaki组
通讯作者	Cheng, Tao; Zhang, Qing; Gao, Chuanbo
作者单位	1.Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Multiphase Flow Power Engn, Xian 710054, Shaanxi, Peoples R China 2.Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Joint Int Res Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Jiangsu, Peoples R China 3.ShanghaiTech Univ, Ctr High resolut Electron Microscopy ChEM, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 4.ShanghaiTech Univ, Shanghai Key Lab High resolut Electron Microscopy, Shanghai 201210, Peoples R China
通讯作者单位	物质科学与技术学院; 上海科技大学
推荐引用方式 GB/T 7714	Liu, Kai,Yang, Hao,Jiang, Yilan,et al. Coherent hexagonal platinum skin on nickel nanocrystals for enhanced hydrogen evolution activity[J]. NATURE COMMUNICATIONS,2023,14(1).
APA	Liu, Kai.,Yang, Hao.,Jiang, Yilan.,Liu, Zhaojun.,Zhang, Shumeng.,...&Gao, Chuanbo.(2023).Coherent hexagonal platinum skin on nickel nanocrystals for enhanced hydrogen evolution activity.NATURE COMMUNICATIONS,14(1).
MLA	Liu, Kai,et al."Coherent hexagonal platinum skin on nickel nanocrystals for enhanced hydrogen evolution activity".NATURE COMMUNICATIONS 14.1(2023).