Fluoroborophosphates: a family of potential deep ultraviolet NLO materials

doi:10.1039/c9qi00006b

	Fluoroborophosphates: a family of potential deep ultraviolet NLO materials
	Wu, Baolin1,2,3,4 ; Hu, Chunli 1; Tang, Ruling1,2,3 ; Mao, Feifei 1; Feng, Jianghe 1; Mao, Jianggao1
	2019-03
发表期刊	INORGANIC CHEMISTRY FRONTIERS (IF:6.1[JCR-2023],5.9[5-Year])
ISSN	2052-1553
卷号	6 期号:3 页码:723-730
发表状态	已发表
DOI	10.1039/c9qi00006b
摘要	A series of new acentric fluoroborophosphates, namely, RbBPO4F, CsBPO4F and (NH4)(2)BPO4F2, have been obtained by combining BO3F or BO2F2 with a PO4 tetrahedron. The structures of the isomeric RbBPO4F and CsBPO4F feature a three-dimensional diamond framework, in which a BO3F (or PO4) tetrahedron corner is shared with three PO4 (or BO3F) tetrahedra, forming 1D tunnels of eight-membered rings (MRs) along the three axial directions, which are filled with alkali cations. (NH4)(2)BPO4F2 exhibits a 3D supramolecular structure, in which 1D [BPO4F2](infinity)(1) anionic chains along the a axes based on corner-sharing and alternating PO4 and BO2F2 tetrahedra are further interconnected with ammonium cations by electrostatic attractions and hydrogen bonds. RbBPO4F, CsBPO4F and (NH4)(2)BPO4F2 display second-harmonic generation (SHG) signals approximately 0.4, 0.6 and 0.8 times that of KH2PO4 (KDP) and exhibit short UV absorption edges (< 200 nm). Measurements of thermal stability and optical properties and theoretical calculations have also been performed.
收录类别	SCI ; SCIE ; EI
语种	英语
资助项目	Strategic Priority Research Program of the Chinese Academy of Sciences[XDB20000000]
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000461092500009
出版者	ROYAL SOC CHEMISTRY
EI入藏号	20191106640674
EI主题词	Computational mechanics ; Geometry ; Harmonic generation ; Hydrogen bonds ; Nonlinear optics ; Optical properties ; Positive ions
EI分类号	Light/Optics:741.1 ; Nonlinear Optics:741.1.1 ; Physical Chemistry:801.4 ; Mathematics:921
WOS关键词	NONLINEAR-OPTICAL MATERIALS ; BOND-VALENCE PARAMETERS ; CRYSTAL-STRUCTURE ; PHOSPHATES ; RB
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/30424
专题	物质科学与技术学院_硕士生物质科学与技术学院_特聘教授组_毛江高组物质科学与技术学院_博士生
通讯作者	Mao, Jianggao
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China 2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
第一作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Wu, Baolin,Hu, Chunli,Tang, Ruling,et al. Fluoroborophosphates: a family of potential deep ultraviolet NLO materials[J]. INORGANIC CHEMISTRY FRONTIERS,2019,6(3):723-730.
APA	Wu, Baolin,Hu, Chunli,Tang, Ruling,Mao, Feifei,Feng, Jianghe,&Mao, Jianggao.(2019).Fluoroborophosphates: a family of potential deep ultraviolet NLO materials.INORGANIC CHEMISTRY FRONTIERS,6(3),723-730.
MLA	Wu, Baolin,et al."Fluoroborophosphates: a family of potential deep ultraviolet NLO materials".INORGANIC CHEMISTRY FRONTIERS 6.3(2019):723-730.