Controlled Synthesis and Optical Properties of Lanthanide-doped Na3ZrF7 Nanocrystals

doi:10.14102/j.cnki.0254-5861.2011-2028

	Controlled Synthesis and Optical Properties of Lanthanide-doped Na3ZrF7 Nanocrystals
	Fu Hu-Hui1,2,3,4 ; Liu Yong-Sheng 1,2; Jiang Fei-Long 1; Hong Mao-Chun1,2,3
	2018-11-12
发表期刊	CHINESE JOURNAL OF STRUCTURAL CHEMISTRY (IF:5.9[JCR-2023],2.1[5-Year])
ISSN	0254-5861
卷号	37 期号:11 页码:1737-1748
发表状态	已发表
DOI	10.14102/j.cnki.0254-5861.2011-2028
摘要	In this paper, we report for the first time the controlled synthesis of lanthanide ion (Ln(3+))-doped tetragonal-phase Na3ZrF7 nanocrystals (NCs) via a high-temperature co-precipitation approach. The as-synthesized Na3ZrF7 NCs are systematically studied by utilizing the XRD, TEM as well as high-resolution photoluminescence (PL) spectroscopy. The morphology and size for the as-synthesized Na3ZrF7 NCs can be finely controlled by changing the experimental parameters such as the amount of precursor, solvent ratio, reaction temperature and time. By utilizing the red-emitting Eu3+ ion as an efficient optical/structural probe, the successful hetero-valence doping of Ln(3+) activators in the lattices of Na3ZrF7 NCs is well-established regardless of their different valences and radii between host Zr4+ ion and Ln(3+) dopant. As a result, intense upconversion (UC) luminescence (UCL) ranging from UV to visible and to NIR spectral regions can be readily achieved after the doping of typical UCL couples of Yb3+/Er3+ , Yb3+/Tm3+ and Yb3+/Ho3+ into the lattices of Na3ZrF7 NCs when excited by using a 980-nm NIR diode laser.
关键词	lanthanide ion Na3ZrF7 nanocrystals upconversion luminescence
收录类别	SCI ; SCIE
语种	英语
资助项目	Natural Science Foundation of Fujian Province[2017J01038]
WOS研究方向	Chemistry ; Crystallography
WOS类目	Chemistry, Inorganic & Nuclear ; Crystallography
WOS记录号	WOS:000454266500007
出版者	CHINESE JOURNAL STRUCTURAL CHEMISTRY
WOS关键词	UP-CONVERSION NANOPARTICLES ; UPCONVERTING NANOPARTICLES ; SIMULTANEOUS ENHANCEMENT ; PHOTODYNAMIC THERAPY ; NANOPROBES ; CONTRAST ; PHOTOLUMINESCENCE ; NANOCOMPOSITE ; NANOPLATFORM ; NAGDF4
原始文献类型	Article
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/30016
专题	物质科学与技术学院_博士生物质科学与技术学院_特聘教授组_洪茂椿组
通讯作者	Liu Yong-Sheng; Jiang Fei-Long; Hong Mao-Chun
作者单位	1.Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Shanghai Tech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Fu Hu-Hui,Liu Yong-Sheng,Jiang Fei-Long,et al. Controlled Synthesis and Optical Properties of Lanthanide-doped Na3ZrF7 Nanocrystals[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2018,37(11):1737-1748.
APA	Fu Hu-Hui,Liu Yong-Sheng,Jiang Fei-Long,&Hong Mao-Chun.(2018).Controlled Synthesis and Optical Properties of Lanthanide-doped Na3ZrF7 Nanocrystals.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,37(11),1737-1748.
MLA	Fu Hu-Hui,et al."Controlled Synthesis and Optical Properties of Lanthanide-doped Na3ZrF7 Nanocrystals".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 37.11(2018):1737-1748.