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Exploring the morphological effect of Ni-x Mg1-xO catalysts on CO2 reforming of methane
2017-05
发表期刊JOURNAL OF ENERGY CHEMISTRY (IF:14.0[JCR-2023],12.3[5-Year])
ISSN2095-4956
卷号26期号:3页码:325-329
发表状态已发表
DOI10.1016/j.jechem.2017.03.010
摘要To gain deep insight into the Morphological effect of NixMg1 (-) O-x catalysts on the reaction of CO2 reforming with methane, we designed and fabricated three different spatial structural NixMg1 (-) O-x catalysts. These NixMg1 (-) O-x catalysts with specific models such as rod, sheet and sphere, exhibited various activity and stability in CO2 reforming reaction. Herein NixMg1 (-) O-x nanorods displayed higher catalytic activity, in which methane conversion was up to 72% and CO2 conversion was 64% at 670 degrees C with a space velocity of 79,200 mL/(g(cat) h), compared with nanosheet and nanosphere counterparts. Furthermore, both catalysts of NixMg1 (-) O-x nanorod and nanosheet showed a high resistance toward coke deposition and sintering of active sites in the process of CO2 reforming of methane. (C) 2017 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
关键词CO2 reforming CH4 conversion Nix Mg1-xO Reactivity Carbon deposition
收录类别SCI ; EI
语种英语
资助项目Strategic Priority Research Program of the Chinese Academy of Sciences[XDA07040200]
WOS研究方向Chemistry ; Energy & Fuels ; Engineering
WOS类目Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS记录号WOS:000404653700001
出版者ELSEVIER SCIENCE BV
EI入藏号20171503569923
EI主题词Carbon ; Carbon dioxide ; Catalysts ; Deposition ; Methane ; Nanorods ; Nanosheets ; Nickel ; Reactivity (nuclear) ; Reforming reactions ; Sintering
WOS关键词SOLID-SOLUTION CATALYSTS ; CARBON-DIOXIDE ; SYNTHESIS GAS ; DEPOSITION ; SYNGAS ; CH4
原始文献类型Article
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/2927
专题物质科学与技术学院
物质科学与技术学院_特聘教授组_孙予罕组
物质科学与技术学院_特聘教授组_祝艳组
物质科学与技术学院_硕士生
通讯作者Sun, Yuhan; Zhu, Yan
作者单位
1.Chinese Acad Sci, CAS Key Lab Low Carbon Convers Sci & Engn, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
第一作者单位物质科学与技术学院
通讯作者单位物质科学与技术学院
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GB/T 7714
Xiao, Qinglin,Xu, Jiayu,Zhang, Jun,et al. Exploring the morphological effect of Ni-x Mg1-xO catalysts on CO2 reforming of methane[J]. JOURNAL OF ENERGY CHEMISTRY,2017,26(3):325-329.
APA Xiao, Qinglin,Xu, Jiayu,Zhang, Jun,Sun, Yuhan,&Zhu, Yan.(2017).Exploring the morphological effect of Ni-x Mg1-xO catalysts on CO2 reforming of methane.JOURNAL OF ENERGY CHEMISTRY,26(3),325-329.
MLA Xiao, Qinglin,et al."Exploring the morphological effect of Ni-x Mg1-xO catalysts on CO2 reforming of methane".JOURNAL OF ENERGY CHEMISTRY 26.3(2017):325-329.
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