Selective oxidation of benzylic alcohols via synergistic bisphosphonium and cobalt catalysis

doi:10.1039/d3cc00532a

	Selective oxidation of benzylic alcohols via synergistic bisphosphonium and cobalt catalysis
	Ding, Jia1,2 ; Luo, Shuaishuai1,2 ; Xu, Yuanli 3; An, Qing1 ; Yang, Yi 3; Zuo, Zhiwei 2
	2023-03-01
发表期刊	CHEMICAL COMMUNICATIONS (IF:4.3[JCR-2023],4.4[5-Year])
ISSN	1359-7345
EISSN	1364-548X
卷号	59 期号:27 页码:4055-4058
发表状态	已发表
DOI	10.1039/d3cc00532a
摘要	A synergistic photocatalytic system using a bisphosphonium catalyst and a cobalt catalyst has been developed, enabling the selective oxidation of benzylic alcohols under oxidant-free and environmentally benign conditions. High efficiencies have been obtained for a variety of alcohol substrates, and exclusive selectivity for aldehyde products has been achieved across the board. Furthermore, this photocatalytic system proved to be efficient when performed under continuous-flow conditions, even using a simple and easily assembled continuous-flow setup.
关键词	Cobalt Benzylic alcohols Cobalt catalysis Cobalt Catalyst Condition Continuous-flow Environmentally benign Higher efficiency Photocatalytic systems Selective oxidation ]+ catalyst
URL	查看原文
收录类别	SCI ; EI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000950884300001
出版者	ROYAL SOC CHEMISTRY
EI入藏号	20231313813432
EI主题词	Catalysts
EI分类号	549.3 Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals ; 803 Chemical Agents and Basic Industrial Chemicals ; 804 Chemical Products Generally
原始文献类型	Journal article (JA)
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/290006
专题	物质科学与技术学院物质科学与技术学院_硕士生物质科学与技术学院_博士生
通讯作者	Yang, Yi; Zuo, Zhiwei
作者单位	1.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 3.Sichuan Univ Sci & Engn, Key Lab Green Chem Sichuan Inst Higher Educ, Innovat Ctr Chenguang High Performance Fluorine Ma, Zigong 643000, Peoples R China
第一作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Ding, Jia,Luo, Shuaishuai,Xu, Yuanli,et al. Selective oxidation of benzylic alcohols via synergistic bisphosphonium and cobalt catalysis[J]. CHEMICAL COMMUNICATIONS,2023,59(27):4055-4058.
APA	Ding, Jia,Luo, Shuaishuai,Xu, Yuanli,An, Qing,Yang, Yi,&Zuo, Zhiwei.(2023).Selective oxidation of benzylic alcohols via synergistic bisphosphonium and cobalt catalysis.CHEMICAL COMMUNICATIONS,59(27),4055-4058.
MLA	Ding, Jia,et al."Selective oxidation of benzylic alcohols via synergistic bisphosphonium and cobalt catalysis".CHEMICAL COMMUNICATIONS 59.27(2023):4055-4058.