Generating carbon schwarzites via zeolite-templating

doi:10.1073/pnas.1805062115

	Generating carbon schwarzites via zeolite-templating
	Braun, Efrem 1; Lee, Yongjin2,3 ; Moosavi, Seyed Mohamad 2; Barthel, Senja 2; Mercado, Rocio 4; Baburin, Igor A.5; Proserpio, Davide M.6,7; Smit, Berend 1,2
	2018-08-28
发表期刊	PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
ISSN	0027-8424
卷号	115 期号:35 页码:EB116-EB124
发表状态	已发表
DOI	10.1073/pnas.1805062115
摘要	Zeolite-templated carbons (ZTCs) comprise a relatively recent material class synthesized via the chemical vapor deposition of a carbon-containing precursor on a zeolite template, followed by the removal of the template. We have developed a theoretical framework to generate a ZTC model from any given zeolite structure, which we show can successfully predict the structure of known ZTCs. We use our method to generate a library of ZTCs from all known zeolites, to establish criteria for which zeolites can produce experimentally accessible ZTCs, and to identify over 10 ZTCs that have never before been synthesized. We show that ZTCs partition space into two disjoint labyrinths that can be described by a pair of interpenetrating nets. Since such a pair of nets also describes a triply periodic minimal surface (TPMS), our results establish the relationship between ZTCs and schwarzites-carbon materials with negative Gaussian curvature that resemble TPMSs-linking the research topics and demonstrating that schwarzites should no longer be thought of as purely hypothetical materials.
关键词	schwarzite zeolite-templated carbon triply periodic minimal surface template carbonization microporous carbon
收录类别	SCI ; SCIE
语种	英语
资助项目	European Research Council (ERC) under the European Union[666983]
WOS研究方向	Science & Technology - Other Topics
WOS类目	Multidisciplinary Sciences
WOS记录号	WOS:000442861600007
出版者	NATL ACAD SCIENCES
WOS关键词	PERIODIC MINIMAL-SURFACES ; NETS ; ALGORITHMS ; FRAMEWORKS ; GEOMETRY ; DATABASE ; REPLICA ; TILINGS ; RANGE
原始文献类型	Article
引用统计
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/27610
专题	物质科学与技术学院_PI研究组_yongjin lee组
通讯作者	Smit, Berend
作者单位	1.Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA 2.EPFL, ISIC, CH-1951 Sion, Switzerland 3.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 4.Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA 5.Tech Univ Dresden, Theoret Chem, D-01062 Dresden, Germany 6.Univ Milan, Dipartimento Chim, I-20133 Milan, Italy 7.Samara State Tech Univ, SCTMS, Samara 443100, Russia
推荐引用方式 GB/T 7714	Braun, Efrem,Lee, Yongjin,Moosavi, Seyed Mohamad,et al. Generating carbon schwarzites via zeolite-templating[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,2018,115(35):EB116-EB124.
APA	Braun, Efrem.,Lee, Yongjin.,Moosavi, Seyed Mohamad.,Barthel, Senja.,Mercado, Rocio.,...&Smit, Berend.(2018).Generating carbon schwarzites via zeolite-templating.PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,115(35),EB116-EB124.
MLA	Braun, Efrem,et al."Generating carbon schwarzites via zeolite-templating".PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA 115.35(2018):EB116-EB124.