Dual-Emitting UiO-66(Zr&Eu) Metal-Organic Framework Films for Ratiometric Temperature Sensing
2018-06-20
发表期刊ACS APPLIED MATERIALS & INTERFACES (IF:8.3[JCR-2023],8.7[5-Year])
ISSN1944-8244
卷号10期号:24页码:20854-20861
发表状态已发表
DOI10.1021/acsami.8b04889
摘要A novel dual-emitting metal-organic framework based on Zr and Eu, named as UiO-66(Zr&Eu), was built using a clever strategy based on secondary building units. With the use of polymers, the obtained UiO-66(Zr&Eu) was subsequently deposited as thin films that can be utilized as smart thermometers. The UiO-66(Zr&Eu) polymer films can be used for the detection of temperature changes in the range of 237-337 K due to the energy transfer between the lanthanide ions (Eu in clusters) and the luminescent ligands, and the relative sensitivity reaches 4.26% K-1 at 337 K. Moreover, the sensitivity can be improved to 19.67% K-1 by changing the film thickness. In addition, the temperature-sensing performance of the films is superior to that of the powders, and the sensor can be reused 3 times without loss of performance.
关键词metal-organic frameworks polymer film mixed-matrix dual-emitting ratiometric temperature sensing
收录类别SCI ; SCIE ; EI
语种英语
资助项目Strategic Priority Research Program of the Chinese Academy of Sciences[XDA20000000]
WOS研究方向Science & Technology - Other Topics ; Materials Science
WOS类目Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号WOS:000436211500071
出版者AMER CHEMICAL SOC
EI入藏号20182305287411
EI主题词Crystalline materials ; Energy transfer ; Organometallics ; Temperature sensors ; Thin films
WOS关键词MIXED-MATRIX MEMBRANES ; ELECTROPHORETIC DEPOSITION ; CO2 CAPTURE ; LUMINESCENT ; MOF ; GAS ; SEPARATION ; NANOPARTICLES ; THERMOMETER ; FABRICATION
原始文献类型Article
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/27440
专题物质科学与技术学院
物质科学与技术学院_特聘教授组_曹荣组
物质科学与技术学院_特聘教授组_施剑林组
物质科学与技术学院_博士生
通讯作者Cao, Rong
作者单位
1.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
2.Chinese Acad Sci, Fujian Inst Res Struct Mater, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位物质科学与技术学院
通讯作者单位物质科学与技术学院
第一作者的第一单位物质科学与技术学院
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GB/T 7714
Feng, Ji-fei,Liu, Tian-fu,Shi, Jianlin,et al. Dual-Emitting UiO-66(Zr&Eu) Metal-Organic Framework Films for Ratiometric Temperature Sensing[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(24):20854-20861.
APA Feng, Ji-fei,Liu, Tian-fu,Shi, Jianlin,Gao, Shui-ying,&Cao, Rong.(2018).Dual-Emitting UiO-66(Zr&Eu) Metal-Organic Framework Films for Ratiometric Temperature Sensing.ACS APPLIED MATERIALS & INTERFACES,10(24),20854-20861.
MLA Feng, Ji-fei,et al."Dual-Emitting UiO-66(Zr&Eu) Metal-Organic Framework Films for Ratiometric Temperature Sensing".ACS APPLIED MATERIALS & INTERFACES 10.24(2018):20854-20861.
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