Gold(I)-catalyzed rearrangement of glycosyl ortho-allenylbenzoates leading to the formation of C-glycosides

doi:10.1016/j.tet.2022.133145

	Gold(I)-catalyzed rearrangement of glycosyl ortho-allenylbenzoates leading to the formation of C-glycosides
	Chen, Jianpeng1 ; Tang, Yu 2; Yu, Biao 2
	2022-12-17
发表期刊	TETRAHEDRON (IF:2.1[JCR-2023],1.8[5-Year])
ISSN	0040-4020
EISSN	1464-5416
卷号	129
发表状态	已发表
DOI	10.1016/j.tet.2022.133145
摘要	A gold(I)-catalyzed rearrangement of glycosyl ortho-allenylbenzoates leading to the formation of C -glycosides has been disclosed. The reaction proceeds via fragmentation of the glycosyl ortho-alle-nylbenzoate into glycosyl cation and 3-[phosphine gold(I)methyl]-1H-isochrmen-1-one intermediates and their subsequent recombination, with the later allyl gold(I) intermediate being successfully trapped and characterized.(c) 2022 Elsevier Ltd. All rights reserved.
关键词	Glycosyl ortho -allenylbenzoate Gold(I) catalysis Alkyl gold(I) complex Rearrangement reaction C-glycosides
URL	查看原文
收录类别	SCI
语种	英语
资助项目	[2021251] ; [ZDBS-LY-SLH030] ; [21871290] ; [22031011]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000902017800007
出版者	PERGAMON-ELSEVIER SCIENCE LTD
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/272809
专题	物质科学与技术学院物质科学与技术学院_硕士生
通讯作者	Tang, Yu; Yu, Biao
作者单位	1.ShanghaiTech Univ, Sch Phys Sci & Technol, 100 Haike Rd, Shanghai 201210, Peoples R China 2.Univ Chinese Acad Sci, Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China
第一作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Chen, Jianpeng,Tang, Yu,Yu, Biao. Gold(I)-catalyzed rearrangement of glycosyl ortho-allenylbenzoates leading to the formation of C-glycosides[J]. TETRAHEDRON,2022,129.
APA	Chen, Jianpeng,Tang, Yu,&Yu, Biao.(2022).Gold(I)-catalyzed rearrangement of glycosyl ortho-allenylbenzoates leading to the formation of C-glycosides.TETRAHEDRON,129.
MLA	Chen, Jianpeng,et al."Gold(I)-catalyzed rearrangement of glycosyl ortho-allenylbenzoates leading to the formation of C-glycosides".TETRAHEDRON 129(2022).