Enhanced CO2 Photoreduction through Spontaneous Charge Separation in End-Capping Assembly of Heterostructured Covalent-Organic Frameworks

doi:10.1002/anie.202214142

	Enhanced CO2 Photoreduction through Spontaneous Charge Separation in End-Capping Assembly of Heterostructured Covalent-Organic Frameworks
	Lin, Huaxing 1; Liu, Yuan 2; Wang, Zirui1,3 ; Ling, Liying 4; Huang, Hao 1; Li, Qiaohong 1; Cheng, Linxiu 5; Li, Yibao 4; Zhou, Jilong 6; Wu, Kaifeng 2; Zhang, Jian 1,7; Zhou, Tianhua 1,7
	2022-11
发表期刊	ANGEWANDTE CHEMIE - INTERNATIONAL EDITION (IF:16.1[JCR-2023],16.2[5-Year])
ISSN	1433-7851
EISSN	1521-3773
卷号	61 期号:50
发表状态	已发表
DOI	10.1002/anie.202214142
摘要	It is well known that charge separation is crucial for efficient photocatalytic solar conversion. Although some covalent-organic frameworks (COFs) exhibit visible-light harvest, the large exciton binding energies reduce their photocatalytic efficiencies. Herein, we developed a novel method to post-treat the olefin-linked COFs with end-capping polycyclic aromatic hydrocarbons (PAHs) for spontaneous charge separation. Interestingly, a type-II heterostructure is constructed in our perylene-modified COFs which displays drastically enhanced performance for photocatalytic CO2 reduction, with an efficiency of 8-fold higher than that of unmodified COF. A combination of electrochemical, steady-state, and time-resolved spectroscopic measurements indicates that such drastically enhanced performance should be attributed to photoinduced spontaneous charge separation in the heterostructure. These results illustrate the feasibility of engineering the charge-separation properties of crystalline porous frameworks at a molecular level for artificial photosynthesis. © 2022 Wiley-VCH GmbH.
关键词	Artificial photosynthesis Binding energy Carbon dioxide Efficiency Electron transitions Photocatalytic activity Reduction Separation Charge-separation CO 2 reduction Covalent organic frameworks End capping Exciton-binding energy Performance Photo reduction Photo-catalytic Postsynthetic modification Visible light
URL	查看原文
收录类别	SCI ; SCIE ; EI
语种	英语
资助项目	National Natural Science Foundation of China[
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000880976600001
出版者	John Wiley and Sons Inc
EI入藏号	20224613110204
EI主题词	Polycyclic aromatic hydrocarbons
EI分类号	657.1 Solar Energy and Phenomena ; 801.4 Physical Chemistry ; 802.2 Chemical Reactions ; 802.3 Chemical Operations ; 804.1 Organic Compounds ; 804.2 Inorganic Compounds ; 913.1 Production Engineering
原始文献类型	Article in Press
Scopus 记录号	2-s2.0-85141714717
来源库	Scopus
引用统计	被引频次：92[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/248920
专题	物质科学与技术学院物质科学与技术学院_博士生
作者单位	1.State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian,350108,China 2.State Key Laboratory of Molecular Reaction Dynamics,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian,Liaoning,116023,China 3.School of Physical Science and Technology,ShanghaiTech University,Shanghai,201210,China 4.Jiangxi Key Laboratory of Organic-Pharmaceutical Chemistry,College of Chemistry and Chemical Engineering,Gannan Normal University,Ganzhou,Jiangxi,341000,China 5.College of Geography and Environmental Engineering,Gannan Normal University,Ganzhou,Jiangxi,341000,China 6.School of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou,510006,China 7.University of Chinese Academy of Sciences,Beijing,100049,China
推荐引用方式 GB/T 7714	Lin, Huaxing,Liu, Yuan,Wang, Zirui,et al. Enhanced CO2 Photoreduction through Spontaneous Charge Separation in End-Capping Assembly of Heterostructured Covalent-Organic Frameworks[J]. ANGEWANDTE CHEMIE - INTERNATIONAL EDITION,2022,61(50).
APA	Lin, Huaxing.,Liu, Yuan.,Wang, Zirui.,Ling, Liying.,Huang, Hao.,...&Zhou, Tianhua.(2022).Enhanced CO2 Photoreduction through Spontaneous Charge Separation in End-Capping Assembly of Heterostructured Covalent-Organic Frameworks.ANGEWANDTE CHEMIE - INTERNATIONAL EDITION,61(50).
MLA	Lin, Huaxing,et al."Enhanced CO2 Photoreduction through Spontaneous Charge Separation in End-Capping Assembly of Heterostructured Covalent-Organic Frameworks".ANGEWANDTE CHEMIE - INTERNATIONAL EDITION 61.50(2022).