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Photo-Induced Programmable Morphological Transition of the Hybrid Coassembles
2018-06
发表期刊MACROMOLECULAR CHEMISTRY AND PHYSICS (IF:2.5[JCR-2023],2.5[5-Year])
ISSN1022-1352
卷号219期号:11
发表状态已发表
DOI10.1002/macp.201800054
摘要Morphology and nanoparticle's distribution are both key factors to the hybrid coassemblies. A fancy method to dynamically control the morphology of hybrid core-shell microspheres (CSMs) with UV light is introduced. The CSMs used here are fabricated with azobenzene (AZO) ended hyperbranched poly(ether amine) in the shell and AZO containing polyhedral oligomer silsesquioxane in the core through coassembly. Upon UV irradiation, the dynamic morphology transition from core-shell microsphere to vesicle is realized by synergistic effects and photothermal effects of AZO, resulting in the size of coassemblies increasing from 1.2 to 2.5 mu m. And versatile multivesicular structures can be fixed and captured as mid-states in taking advantage of the easy control of ON/OFF of UV light. This programmable morphology transition provides a new insight for fabricating light-controlled hybrid materials with ideal structure in soft nanotechnology which matches with requirements in in situ tunable functions, controlled release, and so on.
关键词dynamic control hybrid coassembles morphology transitions photoinduced
收录类别SCI ; SCIE ; EI
语种英语
资助项目Shanghai Municipal Government[15SG13] ; Shanghai Municipal Government[17JC1400700]
WOS研究方向Polymer Science
WOS类目Polymer Science
WOS记录号WOS:000434228200009
出版者WILEY-V C H VERLAG GMBH
WOS关键词LIGHT ; NANOPARTICLES ; VESICLES ; MICELLES ; POLYMERS ; DISSOCIATION ; ASSEMBLIES ; NANOFIBERS ; LOCATION ; SIZE
原始文献类型Article
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/23091
专题物质科学与技术学院
物质科学与技术学院_外聘教师
通讯作者Jiang, Xuesong
作者单位
1.Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, State Key Lab Met Matrix Composite Mat, Shanghai 200240, Peoples R China
2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
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GB/T 7714
Li, Jin,Su, Zhilong,Xu, Hongjie,et al. Photo-Induced Programmable Morphological Transition of the Hybrid Coassembles[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2018,219(11).
APA Li, Jin,Su, Zhilong,Xu, Hongjie,Ma, Xiaodong,Yin, Jie,&Jiang, Xuesong.(2018).Photo-Induced Programmable Morphological Transition of the Hybrid Coassembles.MACROMOLECULAR CHEMISTRY AND PHYSICS,219(11).
MLA Li, Jin,et al."Photo-Induced Programmable Morphological Transition of the Hybrid Coassembles".MACROMOLECULAR CHEMISTRY AND PHYSICS 219.11(2018).
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