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Processable Aqueous Dispersions of Graphene Stabilized by Graphene Quantum Dots
2015-01-13
发表期刊CHEMISTRY OF MATERIALS (IF:7.2[JCR-2023],8.4[5-Year])
ISSN0897-4756
卷号27期号:1页码:218-226
发表状态已发表
DOI10.1021/cm503782p
摘要Dispersing graphene in various solvents is one of the key technologies toward the practical applications of graphene. Herein, using graphene quantum dots (GQDs) as stabilizer, aqueous dispersions of graphene with good stability were demonstrated by directly dispersing commercialized graphene powder into water. Amazingly, 100 mg of graphene powder could be stabilized by an average of merely 7.8 mg GQDs to form aqueous dispersions with a maximum concentration of up to 0.4 mg/mL and stability at least 3 months. The introduction of a small amount of GQDs also allowed for the fabrication of water-redispersible graphene slurry and powder, which would largely facilitate the transportation and applications of graphene. The mechanism of the GQDs stabilized graphene in water was proposed and experimentally verified through UV-visible spectroscopy and zeta potential measurements. Moreover, flexible graphene papers directly assembled from the water-dispersible graphene exhibited controllable thickness, good conductivity, and acceptable strength. With properties not compromised by GQDs, water-dispersible graphene is expected to be widely applicable in electrical and electrochemical device fields.
收录类别SCI ; EI
语种英语
资助项目Chinese Academy of Sciences[KGZD-EW-303] ; Chinese Academy of Sciences[XDA02040000]
WOS研究方向Chemistry ; Materials Science
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary
WOS记录号WOS:000348085300029
出版者AMER CHEMICAL SOC
EI入藏号20150400442564
EI主题词Dispersions ; Nanocrystals ; Semiconductor quantum dots ; Ultraviolet visible spectroscopy
EI分类号Semiconductor Devices and Integrated Circuits:714.2 ; Optical Devices and Systems:741.3 ; Nanotechnology:761 ; Chemical Products Generally:804 ; Materials Science:951
WOS关键词FUNCTIONALIZED GRAPHENE ; SHEETS ; EXFOLIATION ; OXIDE ; GRAPHITE ; PAPER ; SUPERCAPACITORS ; NANOSHEETS ; HYDROGEL ; STORAGE
原始文献类型Article
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/2270
专题物质科学与技术学院
物质科学与技术学院_博士生
通讯作者Ding, Guqiao
作者单位
1.Chinese Acad Sci, Shanghai Inst Microsyst & Informat Technol, State Key Lab Funct Mat Informat, Shanghai 200050, Peoples R China
2.Shanghai Tech Univ, Sch Phys Sci & Technol, Shanghai 200031, Peoples R China
推荐引用方式
GB/T 7714
He, Peng,Sun, Jing,Tian, Suyun,et al. Processable Aqueous Dispersions of Graphene Stabilized by Graphene Quantum Dots[J]. CHEMISTRY OF MATERIALS,2015,27(1):218-226.
APA He, Peng.,Sun, Jing.,Tian, Suyun.,Yang, Siwei.,Ding, Shengju.,...&Jiang, Mianheng.(2015).Processable Aqueous Dispersions of Graphene Stabilized by Graphene Quantum Dots.CHEMISTRY OF MATERIALS,27(1),218-226.
MLA He, Peng,et al."Processable Aqueous Dispersions of Graphene Stabilized by Graphene Quantum Dots".CHEMISTRY OF MATERIALS 27.1(2015):218-226.
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