Ultramicroporous Organophosphorus Polymers via Self-Accelerating P-C Coupling Reaction: Kinetic Effects on Crosslinking Environments and Porous Structures

doi:10.1021/jacs.2c03759

	Ultramicroporous Organophosphorus Polymers via Self-Accelerating P-C Coupling Reaction: Kinetic Effects on Crosslinking Environments and Porous Structures
	Zhang, Zhikai; Wang, Qing; Liu, Haiming; Li, Tao; Ren, Yi
	2022-07-06
发表期刊	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (IF:14.4[JCR-2023],14.8[5-Year])
ISSN	0002-7863
EISSN	1520-5126
发表状态	已发表
DOI	10.1021/jacs.2c03759
摘要	Porous organic polymers (POPs) have drawn significant attention in diverse applications. However, factors affecting the heterogeneous polymerization and porosity of POPs are still not well understood. Herein, we report a new strategy to construct porous organophosphorus polymers (POPPs) with high surface areas (1283 m(2)/g) and ultramicroporous structures (0.67 nm). The strategy harnesses an efficient transition-metal-catalyzed phosphorus-carbon (P-C) coupling reaction at the trigonal pyramidal P-center, which is distinct from the typical carbon-carbon coupling reaction utilized in the synthesis of POPs. As the first kinetic study on the coupling reaction of POPs, we uncovered a self-accelerating reaction characteristic, which is controlled by the choice of bases and catalysts. The self-accelerating characteristic of the P-C coupling reaction is beneficial for the high surface area and uniform ultramicroporosity of POPPs. The direct crosslinking of the P-centers allows P-31 solid-state (ss)NMR experiments to unambiguously reveal the crosslinking environments of POPPs. Leveraging on the kinetic studies and P-31 ssNMR studies, we were able to reveal the kinetic effects of the P-C coupling reaction on both the crosslinking environments and the porous structures of POPPs. Furthermore, our studies show that the CO2 uptake capacity of POPPs is highly dependent on their porous structures. Overall, our studies paves the way to design new POPs with better controlled chemical and ultramicroporous structures, which have potential applications for CO2 capture and separation.
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收录类别	SCI ; EI ; SCIE
语种	英语
资助项目	Natural Science Foundation of Shanghai[19ZR1433700] ; Analytical Instrumentation Center, SPST, ShanghaiTech University[SPST-AIC10112914]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000818698500001
出版者	AMER CHEMICAL SOC
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/192381
专题	物质科学与技术学院物质科学与技术学院_PI研究组_李涛组物质科学与技术学院_PI研究组_任毅组物质科学与技术学院_PI研究组_刘海铭组物质科学与技术学院_硕士生
通讯作者	Ren, Yi
作者单位	ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Zhang, Zhikai,Wang, Qing,Liu, Haiming,et al. Ultramicroporous Organophosphorus Polymers via Self-Accelerating P-C Coupling Reaction: Kinetic Effects on Crosslinking Environments and Porous Structures[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2022.
APA	Zhang, Zhikai,Wang, Qing,Liu, Haiming,Li, Tao,&Ren, Yi.(2022).Ultramicroporous Organophosphorus Polymers via Self-Accelerating P-C Coupling Reaction: Kinetic Effects on Crosslinking Environments and Porous Structures.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY.
MLA	Zhang, Zhikai,et al."Ultramicroporous Organophosphorus Polymers via Self-Accelerating P-C Coupling Reaction: Kinetic Effects on Crosslinking Environments and Porous Structures".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022).