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Extraction of boron from salt lake brine using 2-ethylhexanol
2016-03
发表期刊HYDROMETALLURGY (IF:4.8[JCR-2023],4.8[5-Year])
ISSN0304-386X
卷号160页码:129-136
发表状态已发表
DOI10.1016/j.hydromet.2016.01.001
摘要A systematic investigation on the extraction of boron from salt lake brine using 2-ethylhexanol as the extractant is reported with an emphasis on the extraction thermodynamics and extraction process design in order to obtain high purity boron product. The extraction parameters were optimized with respect to the time of extraction, volume percentage of extractant, phase ratio, and the concentration of magnesium. Logarithm linear regression revealed an average association constant of 0.7 for 2-ethylhexanol and boric acid. Thermodynamic modeling results indicate that the association is an exothermic, enthalpy driven process. A three-stage countercurrent extraction and stripping was designed in order to assess the process feasibility. Results showed an overall boron extraction efficiency of 99.5% with a purity of 95.5%. In addition, attempts were also made on improving the product purity with a two-stage washing step. These results indicate the application potential of present extraction process. (C) 2016 Elsevier B.V. All rights reserved.
关键词Boron Solvent extraction 2-Ethylhexanol Salt lake brine Extraction efficiency
收录类别SCI ; EI
语种英语
资助项目Key Research Fund from CAS[Y424541211]
WOS研究方向Metallurgy & Metallurgical Engineering
WOS类目Metallurgy & Metallurgical Engineering
WOS记录号WOS:000371376800016
出版者ELSEVIER SCIENCE BV
EI入藏号20160501855438
EI主题词Boric acid ; Boron ; Efficiency ; Lakes ; Product design ; Solvent extraction ; Thermodynamics
EI分类号Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3 ; Thermodynamics:641.1 ; Chemical Operations:802.3 ; Inorganic Compounds:804.2 ; Production Engineering:913.1
WOS关键词ION-EXCHANGE-RESINS ; SOLVENT-EXTRACTION ; GEOTHERMAL WATER ; SORPTION-ELUTION ; WASTE-WATER ; REMOVAL ; ADSORPTION ; RESOURCES ; KEROSENE ; RECOVERY
原始文献类型Article
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/1915
专题物质科学与技术学院_特聘教授组_何涛组
通讯作者Li, Xue-Mei; He, Tao
作者单位
1.Univ Shanghai Sci & Technol, Sch Energy & Power Engn, Shanghai 200093, Peoples R China
2.Chinese Acad Sci, Shanghai Adv Res Inst, Membrane Mat & Separat Technol, Shanghai 201210, Peoples R China
3.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
通讯作者单位物质科学与技术学院
推荐引用方式
GB/T 7714
Zhang, Ran,Xie, Yingming,Song, Jianfeng,et al. Extraction of boron from salt lake brine using 2-ethylhexanol[J]. HYDROMETALLURGY,2016,160:129-136.
APA Zhang, Ran.,Xie, Yingming.,Song, Jianfeng.,Xing, Lixin.,Kong, Dingfeng.,...&He, Tao.(2016).Extraction of boron from salt lake brine using 2-ethylhexanol.HYDROMETALLURGY,160,129-136.
MLA Zhang, Ran,et al."Extraction of boron from salt lake brine using 2-ethylhexanol".HYDROMETALLURGY 160(2016):129-136.
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