Highly Efficient Synthesis of Functionalizable Polymers from a CO2/1,3-Butadiene-Derived Lactone

doi:10.1021/acsmacrolett.7b00774

	Highly Efficient Synthesis of Functionalizable Polymers from a CO2/1,3-Butadiene-Derived Lactone
	Liu, Muhua1,2,3 ; Sun, Yunyan1 ; Liang, Yuanqi1,2 ; Lin, Bo-Lin1,2,3,4
	2017-12
发表期刊	ACS MACRO LETTERS
ISSN	21611653
卷号	6 期号:12 页码:1373-1378
发表状态	已发表
DOI	10.1021/acsmacrolett.7b00774
摘要	Making polymers from CO2 and olefins has been long sought and is of particular significance for chemical utilizations of CO2. Herein, high molecular-weight polymers with 29 wt % CO2 were obtained by polymerizing a delta-lactone (L) synthesized from a C-C coupling reaction between CO2 and 1,3-butadiene, an economical large-volume chemical that can also be derived from top biomass platform chemicals. Although L has been known for many years, little was investigated in its polymerization. We found that L's polymerizability can be vitalized upon simply heating in the presence of O-2. The polymerization is additive/solvent-free with abundant preserved olefins and up to full monomer conversion, providing a convenient, economical, and scalable avenue to obtain CO2-derived polymers with potentially tailorable properties via the readily modifiable olefins.
收录类别	SCI ; EI
语种	英语
资助项目	National Science Foundation of China (NSFC)[U1532125]
WOS研究方向	Polymer Science
WOS类目	Polymer Science
WOS记录号	WOS:000418636300010
出版者	AMER CHEMICAL SOC
EI入藏号	20175204580042
EI主题词	Chemical bonds ; Esters ; Indicators (chemical) ; Olefins ; Polymerization
EI分类号	Chemistry:801 ; Physical Chemistry:801.4 ; Chemical Products Generally:804 ; Polymerization:815.2
WOS关键词	CARBON-DIOXIDE ; COPOLYMERIZATION ; POLYMERIZATION ; OPTIMIZATION ; BUTADIENE ; EPOXIDES ; TELOMERIZATION ; 1,3-BUTADIENE ; HYDROGENATION ; SELECTIVITY
原始文献类型	Article
引用统计
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/16270
专题	物质科学与技术学院物质科学与技术学院_PI研究组_林柏霖组物质科学与技术学院_硕士生物质科学与技术学院_本科生物质科学与技术学院_博士生
通讯作者	Lin, Bo-Lin
作者单位	1.ShanghaiTech Univ, SPST, Shanghai 201210, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Shanghai Adv Res Inst, Key Lab Low Carbon Convers Sci & Engn, Shanghai 201210, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Liu, Muhua,Sun, Yunyan,Liang, Yuanqi,et al. Highly Efficient Synthesis of Functionalizable Polymers from a CO2/1,3-Butadiene-Derived Lactone[J]. ACS MACRO LETTERS,2017,6(12):1373-1378.
APA	Liu, Muhua,Sun, Yunyan,Liang, Yuanqi,&Lin, Bo-Lin.(2017).Highly Efficient Synthesis of Functionalizable Polymers from a CO2/1,3-Butadiene-Derived Lactone.ACS MACRO LETTERS,6(12),1373-1378.
MLA	Liu, Muhua,et al."Highly Efficient Synthesis of Functionalizable Polymers from a CO2/1,3-Butadiene-Derived Lactone".ACS MACRO LETTERS 6.12(2017):1373-1378.