Highly Efficient Synthesis of Functionalizable Polymers from a CO2/1,3-Butadiene-Derived Lactone
Liu, Muhua1,2,3; Sun, Yunyan1; Liang, Yuanqi1,2; Lin, Bo-Lin1,2,3,4
2017-12
Source PublicationACS MACRO LETTERS
ISSN21611653
Volume6Issue:12Pages:1373-1378
Status已发表
DOI10.1021/acsmacrolett.7b00774
AbstractMaking polymers from CO2 and olefins has been long sought and is of particular significance for chemical utilizations of CO2. Herein, high molecular-weight polymers with 29 wt % CO2 were obtained by polymerizing a delta-lactone (L) synthesized from a C-C coupling reaction between CO2 and 1,3-butadiene, an economical large-volume chemical that can also be derived from top biomass platform chemicals. Although L has been known for many years, little was investigated in its polymerization. We found that L's polymerizability can be vitalized upon simply heating in the presence of O-2. The polymerization is additive/solvent-free with abundant preserved olefins and up to full monomer conversion, providing a convenient, economical, and scalable avenue to obtain CO2-derived polymers with potentially tailorable properties via the readily modifiable olefins.
Indexed BySCI ; EI
Language英语
Funding ProjectNational Science Foundation of China (NSFC)[U1532125]
WOS Research AreaPolymer Science
WOS SubjectPolymer Science
WOS IDWOS:000418636300010
PublisherAMER CHEMICAL SOC
EI Accession Number20175204580042
EI KeywordsChemical bonds ; Esters ; Indicators (chemical) ; Olefins ; Polymerization
EI Classification NumberChemistry:801 ; Physical Chemistry:801.4 ; Chemical Products Generally:804 ; Polymerization:815.2
WOS KeywordCARBON-DIOXIDE ; COPOLYMERIZATION ; POLYMERIZATION ; OPTIMIZATION ; BUTADIENE ; EPOXIDES ; TELOMERIZATION ; 1,3-BUTADIENE ; HYDROGENATION ; SELECTIVITY
Original Document TypeArticle
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttps://kms.shanghaitech.edu.cn/handle/2MSLDSTB/16270
Collection物质科学与技术学院
物质科学与技术学院_PI研究组_林柏霖组
物质科学与技术学院_硕士生
物质科学与技术学院_本科生
物质科学与技术学院_博士生
Corresponding AuthorLin, Bo-Lin
Affiliation1.ShanghaiTech Univ, SPST, Shanghai 201210, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Chinese Acad Sci, Shanghai Adv Res Inst, Key Lab Low Carbon Convers Sci & Engn, Shanghai 201210, Peoples R China
First Author AffilicationSchool of Physical Science and Technology
Corresponding Author AffilicationSchool of Physical Science and Technology
First Signature AffilicationSchool of Physical Science and Technology
Recommended Citation
GB/T 7714
Liu, Muhua,Sun, Yunyan,Liang, Yuanqi,et al. Highly Efficient Synthesis of Functionalizable Polymers from a CO2/1,3-Butadiene-Derived Lactone[J]. ACS MACRO LETTERS,2017,6(12):1373-1378.
APA Liu, Muhua,Sun, Yunyan,Liang, Yuanqi,&Lin, Bo-Lin.(2017).Highly Efficient Synthesis of Functionalizable Polymers from a CO2/1,3-Butadiene-Derived Lactone.ACS MACRO LETTERS,6(12),1373-1378.
MLA Liu, Muhua,et al."Highly Efficient Synthesis of Functionalizable Polymers from a CO2/1,3-Butadiene-Derived Lactone".ACS MACRO LETTERS 6.12(2017):1373-1378.
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