Using a Multi-Shelled Hollow Metal-Organic Framework as a Host to Switch the Guest-to-Host and Guest-to-Guest Interactions

doi:10.1002/anie.201711600

	Using a Multi-Shelled Hollow Metal-Organic Framework as a Host to Switch the Guest-to-Host and Guest-to-Guest Interactions
	Liu, Xiao-Yuan 1,2,3,4; Zhang, Furui 2; Goh, Tian-Wei 5; Li, Yang 2; Shao, Yu-Cai 2; Luo, Lianshun1 ; Huang, Wenyu 5; Long, Yi-Tao 3,4; Chou, Lien-Yang1 ; Tsung, Chia-Kuang2
	2018-02-19
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (IF:16.1[JCR-2023],16.2[5-Year])
ISSN	1433-7851
卷号	57 期号:8 页码:2110-2114
发表状态	已发表
DOI	10.1002/anie.201711600
摘要	A bio-inspired design of using metal-organic framework (MOF) microcrystals with well-defined multi-shelled hollow structures was used as a matrix to host multiple guests including molecules and nanoparticles at separated locations to form a hierarchical material, mimicking biological structures. The interactions such as energy transfer (ET) between different guests are regulated by precisely fixing them in the MOF shells or encapsulating them in the cavities between the MOF shells. The proof-of-concept design is demonstrated by hosting chromophore molecules including rhodamine 6G (R6G) and 7-amino-4-(trifluoromethyl)coumarin (C-151), as well as metal nanoparticles (Pd NPs) into the multi-shelled hollow zeolitic imidazolate framework-8 (ZIF-8). We could selectively establish or diminish the guest-to-framework and guest-to-guest ET. This work provides a platform to construct complex multifunctional materials, especially those need precise separation control of multi-components.
关键词	fluorescence resonance energy transfer metal-organic frameworks multi-shelled hollow structures zeolitic imidazolate frameworks
收录类别	SCI ; SCIE ; EI
语种	英语
资助项目	NSF[CHE 1566445]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000424879400013
出版者	WILEY-V C H VERLAG GMBH
EI入藏号	20180504689680
EI主题词	Biological materials ; Chromophores ; Crystalline materials ; Energy transfer ; Fluorescence ; Metal nanoparticles ; Metals ; Molecules ; Nanoparticles ; Organic polymers ; Organometallics
WOS关键词	DE-NOVO APPROACH ; ENERGY-TRANSFER ; HETEROGENEOUS CATALYSIS ; EMBEDDING ENZYMES ; HYDROGEN STORAGE ; DRUG-DELIVERY ; NANOSTRUCTURES ; NANOPARTICLES ; MICROCRYSTALS ; NANOSPHERES
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/16264
专题	物质科学与技术学院物质科学与技术学院_PI研究组_宗家洸组物质科学与技术学院_特聘教授组_杨培东物质科学与技术学院_硕士生
通讯作者	Huang, Wenyu; Chou, Lien-Yang; Tsung, Chia-Kuang
作者单位	1.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 2.Boston Coll, Merkert Chem Ctr, Dept Chem, Boston, MA 02467 USA 3.East China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China 4.East China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China 5.Iowa State Univ, Dept Chem, Ames, IA 50011 USA
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Liu, Xiao-Yuan,Zhang, Furui,Goh, Tian-Wei,et al. Using a Multi-Shelled Hollow Metal-Organic Framework as a Host to Switch the Guest-to-Host and Guest-to-Guest Interactions[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(8):2110-2114.
APA	Liu, Xiao-Yuan.,Zhang, Furui.,Goh, Tian-Wei.,Li, Yang.,Shao, Yu-Cai.,...&Tsung, Chia-Kuang.(2018).Using a Multi-Shelled Hollow Metal-Organic Framework as a Host to Switch the Guest-to-Host and Guest-to-Guest Interactions.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(8),2110-2114.
MLA	Liu, Xiao-Yuan,et al."Using a Multi-Shelled Hollow Metal-Organic Framework as a Host to Switch the Guest-to-Host and Guest-to-Guest Interactions".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.8(2018):2110-2114.