<p>Surface-Seal Encapsulation of a Homogeneous Catalyst in a Mesoporous Metal-Organic Framework</p>

doi:10.1021/jacs.1c11573

	Surface-Seal Encapsulation of a Homogeneous Catalyst in a Mesoporous Metal-Organic Framework
	Wang, Dongxu; Li, Siqi; Wu, Chunhui; Li, Tao
	2022-01-19
发表期刊	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (IF:14.4[JCR-2023],14.8[5-Year])
ISSN	0002-7863
EISSN	1520-5126
卷号	144 期号:2
发表状态	已发表
DOI	10.1021/jacs.1c11573
摘要	A rapid surface sealing strategy has been developed for the encapsulation of a homogeneous catalyst, phosphotungstic acid (PTA), in a mesoporous metal-organic framework (MOF), MIL-101(Cr). This new surface polymerization method utilizes non-solvent-induced phase separation to concentrate and direct polyamine and dianhydride monomers onto MOF particle surfaces, thus realizing the formation of a sub-10 nm, uniform, and cross-linked polymer coating within a few seconds. While fully preserving the catalytic activity of the neat PTA for the catalytic decomposition of phenol, the surface-sealed PTA-MOF composite catalyst can be reused up to 10 times with no noticeable loss of activity and negligible leaching of PTA. Since this surface coating method is not limited by either the MOF or the catalyst, it will become the technique of choice for the immobilization of homogeneous catalysts in MOFs.
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收录类别	SCI ; SCIE ; EI
语种	英语
资助项目	National Natural Science Foundation of China[22075181] ; Analytical Instrumentation Center, SPST, ShanghaiTech University[SPST-AIC10112914] ; Centre for High-Resolution Electron Microscopy (C.EM) of SPST at ShanghaiTech University[EM02161943]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000745255700001
出版者	AMER CHEMICAL SOC
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/153548
专题	物质科学与技术学院_硕士生物质科学与技术学院_PI研究组_李涛组物质科学与技术学院_博士生
通讯作者	Li, Tao
作者单位	ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Wang, Dongxu,Li, Siqi,Wu, Chunhui,et al. Surface-Seal Encapsulation of a Homogeneous Catalyst in a Mesoporous Metal-Organic Framework [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2022,144(2).
APA	Wang, Dongxu,Li, Siqi,Wu, Chunhui,&Li, Tao.(2022). Surface-Seal Encapsulation of a Homogeneous Catalyst in a Mesoporous Metal-Organic Framework .JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,144(2).
MLA	Wang, Dongxu,et al." Surface-Seal Encapsulation of a Homogeneous Catalyst in a Mesoporous Metal-Organic Framework ".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 144.2(2022).