Grafting nanometer metal/oxide interface towards enhanced low-temperature acetylene semi-hydrogenation

doi:10.1038/s41467-021-25984-8

	Grafting nanometer metal/oxide interface towards enhanced low-temperature acetylene semi-hydrogenation
	Zou, Shihui 1; Lou, Baohui 1; Yang, Kunran2 ; Yuan, Wentao 3; Zhu, Chongzhi 4,5; Zhu, Yihan 4,5; Du, Yonghua 6,7; Lu, Linfang 1; Liu, Juanjuan 8; Huang, Weixin 9; Yang, Bo2 ; Gong, Zhongmiao 10; Cui, Yi 10; Wang, Yong 3; Ma, Lu 7; Ma, Jingyuan 11; Jiang, Zheng 11; Xiao, Liping 1; Fan, Jie 1
	2021
发表期刊	NATURE COMMUNICATIONS (IF:14.7[JCR-2023],16.1[5-Year])
EISSN	2041-1723
卷号	12 期号:1
DOI	10.1038/s41467-021-25984-8
摘要	Metal/oxide interface is of fundamental significance to heterogeneous catalysis. Here, the authors construct a nanometer Pd/Bi2O3 interface by grafting Pd clusters onto Bi2O3 clusters and demonstrate its essential roles in the low-temperature semi-hydrogenation of acetylene. Metal/oxide interface is of fundamental significance to heterogeneous catalysis because the seemingly inert oxide support can modulate the morphology, atomic and electronic structures of the metal catalyst through the interface. The interfacial effects are well studied over a bulk oxide support but remain elusive for nanometer-sized systems like clusters, arising from the challenges associated with chemical synthesis and structural elucidation of such hybrid clusters. We hereby demonstrate the essential catalytic roles of a nanometer metal/oxide interface constructed by a hybrid Pd/Bi2O3 cluster ensemble, which is fabricated by a facile stepwise photochemical method. The Pd/Bi2O3 cluster, of which the hybrid structure is elucidated by combined electron microscopy and microanalysis, features a small Pd-Pd coordination number and more importantly a Pd-Bi spatial correlation ascribed to the heterografting between Pd and Bi terminated Bi2O3 clusters. The intra-cluster electron transfer towards Pd across the as-formed nanometer metal/oxide interface significantly weakens the ethylene adsorption without compromising the hydrogen activation. As a result, a 91% selectivity of ethylene and 90% conversion of acetylene can be achieved in a front-end hydrogenation process with a temperature as low as 44 degrees C.
URL	查看原文
收录类别	SCIE
语种	英语
WOS研究方向	Science & Technology - Other Topics
WOS类目	Multidisciplinary Sciences
WOS记录号	WOS:000702753200010
出版者	NATURE PORTFOLIO
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/128421
专题	物质科学与技术学院_博士生物质科学与技术学院_PI研究组_杨波组
通讯作者	Zou, Shihui; Zhu, Yihan; Du, Yonghua; Yang, Bo; Fan, Jie
作者单位	1.Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310027, Peoples R China; 2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China; 3.Zhejiang Univ, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China; 4.Zhejiang Univ Technol, State Key Lab Breeding Base Green Chem Synth Tech, Ctr Electron Microscopy, Hangzhou 310014, Peoples R China; 5.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China; 6.ASTAR, Inst Chem & Engn Sci, Singapore 627833, Singapore; 7.Brookhaven Natl Lab, Natl Synchrotron Light Source 2, Upton, NY 11973 USA; 8.Hangzhou Dianzi Univ, Coll Mat & Environm Engn, Hangzhou 310036, Peoples R China; 9.Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Peoples R China; 10.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Vacuum Interconnected Nanotech Workstn, Suzhou 215123, Peoples R China; 11.Chinese Acad Sci, Shanghai Synchrotron Radiat Facil, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
通讯作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Zou, Shihui,Lou, Baohui,Yang, Kunran,et al. Grafting nanometer metal/oxide interface towards enhanced low-temperature acetylene semi-hydrogenation[J]. NATURE COMMUNICATIONS,2021,12(1).
APA	Zou, Shihui.,Lou, Baohui.,Yang, Kunran.,Yuan, Wentao.,Zhu, Chongzhi.,...&Fan, Jie.(2021).Grafting nanometer metal/oxide interface towards enhanced low-temperature acetylene semi-hydrogenation.NATURE COMMUNICATIONS,12(1).
MLA	Zou, Shihui,et al."Grafting nanometer metal/oxide interface towards enhanced low-temperature acetylene semi-hydrogenation".NATURE COMMUNICATIONS 12.1(2021).