Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis
Chen, Yuegang1; Wang, Xin1; He, Xu1; An, Qing1; Zuo, Zhiwei2
2021-04-07
发表期刊JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
EISSN1520-5126
卷号143期号:13页码:4896-4902
发表状态已发表
DOI10.1021/jacs.1c00618
摘要

Under mild reaction conditions with inexpensive cerium and nickel catalysts, easily accessible free alcohols can now be utilized as operationally simple and robust carbon pronucleophiles in selective C(sp(3))-C(sp(2)) cross-couplings. Facilitated by automated high-throughput experimentation, sterically encumbered benzoate ligands have been identified for robust cerium complexes, enabling the synergistic cooperation of cerium catalysis in the emerging metallaphotoredox catalysis. A broad range of free alcohols and aromatic halides can be facilely employed in this transformation, representing a new paradigm for the C(sp(3))-C(sp(2)) bond construction between free alcohols and aryl halides with the extrusion of formaldehyde. Moreover, mechanistic investigations have been conducted, leading to the identification of a tribenzoate cerium(III) complex as a viable intermediate.

收录类别SCIE ; EI ; IC
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000639019400005
出版者AMER CHEMICAL SOC
原始文献类型Article
引用统计
文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/126219
专题物质科学与技术学院_硕士生
物质科学与技术学院_PI研究组_左智伟组
物质科学与技术学院_博士生
通讯作者Zuo, Zhiwei
作者单位1.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China;
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
第一作者单位物质科学与技术学院
第一作者的第一单位物质科学与技术学院
推荐引用方式
GB/T 7714
Chen, Yuegang,Wang, Xin,He, Xu,et al. Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2021,143(13):4896-4902.
APA Chen, Yuegang,Wang, Xin,He, Xu,An, Qing,&Zuo, Zhiwei.(2021).Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,143(13),4896-4902.
MLA Chen, Yuegang,et al."Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 143.13(2021):4896-4902.
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