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Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis | |
Chen, Yuegang1; Wang, Xin1; He, Xu1; An, Qing1; Zuo, Zhiwei2 | |
2021-04-07 | |
发表期刊 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY |
ISSN | 0002-7863 |
EISSN | 1520-5126 |
卷号 | 143期号:13页码:4896-4902 |
发表状态 | 已发表 |
DOI | 10.1021/jacs.1c00618 |
摘要 | Under mild reaction conditions with inexpensive cerium and nickel catalysts, easily accessible free alcohols can now be utilized as operationally simple and robust carbon pronucleophiles in selective C(sp(3))-C(sp(2)) cross-couplings. Facilitated by automated high-throughput experimentation, sterically encumbered benzoate ligands have been identified for robust cerium complexes, enabling the synergistic cooperation of cerium catalysis in the emerging metallaphotoredox catalysis. A broad range of free alcohols and aromatic halides can be facilely employed in this transformation, representing a new paradigm for the C(sp(3))-C(sp(2)) bond construction between free alcohols and aryl halides with the extrusion of formaldehyde. Moreover, mechanistic investigations have been conducted, leading to the identification of a tribenzoate cerium(III) complex as a viable intermediate. |
收录类别 | SCIE ; EI ; IC |
语种 | 英语 |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
WOS记录号 | WOS:000639019400005 |
出版者 | AMER CHEMICAL SOC |
原始文献类型 | Article |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/126219 |
专题 | 物质科学与技术学院_硕士生 物质科学与技术学院_PI研究组_左智伟组 物质科学与技术学院_博士生 |
通讯作者 | Zuo, Zhiwei |
作者单位 | 1.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China; 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
第一作者单位 | 物质科学与技术学院 |
第一作者的第一单位 | 物质科学与技术学院 |
推荐引用方式 GB/T 7714 | Chen, Yuegang,Wang, Xin,He, Xu,et al. Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2021,143(13):4896-4902. |
APA | Chen, Yuegang,Wang, Xin,He, Xu,An, Qing,&Zuo, Zhiwei.(2021).Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,143(13),4896-4902. |
MLA | Chen, Yuegang,et al."Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 143.13(2021):4896-4902. |
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