Hf(OTf)(4)-Catalyzed 1,6-Conjugate Addition of 2-Alkyl-azaarenes to para-Quinone Methides

doi:10.1021/acs.joc.0c02982

	Hf(OTf)(4)-Catalyzed 1,6-Conjugate Addition of 2-Alkyl-azaarenes to para-Quinone Methides
	Liu, Xinyuan 1; Liu, Binbin 1; Shi, Zhan2 ; Tan, Chen 1; Fan, Rong 1; Li, Zhi2 ; Tan, Jiajing 1
	2021-02-19
发表期刊	THE JOURNAL OF ORGANIC CHEMISTRY (IF:3.3[JCR-2023],3.2[5-Year])
ISSN	0022-3263
EISSN	1520-6904
卷号	86 期号:4 页码:3615-3624
发表状态	已发表
DOI	10.1021/acs.joc.0c02982
摘要	Herein we reported a Hf(OTf)(4)-catalyzed carbon-carbon bond formation reaction between 2-alkyl-azaarenes and para-quinone methides (p-QMs). This 1,6-conjugate addition protocol offered rapid access to a large array of triarylethane products in good yields. The catalyst loading could be reduced to 1 mol %. Studies pertinent to scale-up reaction and product derivatization were also presented.
关键词	Carbon Chemical bonds 1 ,6 conjugate additions Carbon carbon bond formation reactions Catalyst loadings Derivatizations Large arrays Quinone methides Scale up
收录类别	SCI ; SCIE ; EI ; IC
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000621599900035
出版者	AMER CHEMICAL SOC
EI入藏号	20210709915274
EI主题词	Quinone
EI分类号	801.4 Physical Chemistry ; 804 Chemical Products Generally
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/125791
专题	物质科学与技术学院_硕士生物质科学与技术学院_PI研究组_李智组物质科学与技术学院_博士生
通讯作者	Tan, Jiajing
作者单位	1.Beijing Univ Chem Technol, Coll Chem, Dept Organ Chem, Beijing 100029, Peoples R China; 2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
推荐引用方式 GB/T 7714	Liu, Xinyuan,Liu, Binbin,Shi, Zhan,et al. Hf(OTf)(4)-Catalyzed 1,6-Conjugate Addition of 2-Alkyl-azaarenes to para-Quinone Methides[J]. THE JOURNAL OF ORGANIC CHEMISTRY,2021,86(4):3615-3624.
APA	Liu, Xinyuan.,Liu, Binbin.,Shi, Zhan.,Tan, Chen.,Fan, Rong.,...&Tan, Jiajing.(2021).Hf(OTf)(4)-Catalyzed 1,6-Conjugate Addition of 2-Alkyl-azaarenes to para-Quinone Methides.THE JOURNAL OF ORGANIC CHEMISTRY,86(4),3615-3624.
MLA	Liu, Xinyuan,et al."Hf(OTf)(4)-Catalyzed 1,6-Conjugate Addition of 2-Alkyl-azaarenes to para-Quinone Methides".THE JOURNAL OF ORGANIC CHEMISTRY 86.4(2021):3615-3624.