One-pot Synthesis of Acetals by Tandem Hydroformylation-acetalization of Olefins Using Heterogeneous Supported Catalysts

doi:10.1007/s10562-020-03504-5

	One-pot Synthesis of Acetals by Tandem Hydroformylation-acetalization of Olefins Using Heterogeneous Supported Catalysts
	Li, Xiao 1,2; Qin, Tingting 1,2; Li, Liusha 1,2; Wu, Bo 1,2; Lin, Tiejun 1; Zhong, Liangshu1,3
	2021-09
发表期刊	CATALYSIS LETTERS (IF:2.3[JCR-2023],2.5[5-Year])
ISSN	1011-372X
发表状态	已发表
DOI	10.1007/s10562-020-03504-5
摘要	A green route for one-pot synthesis of acetals by tandem hydroformylation-acetalization of olefins using supported Rh-based catalysts was developed. Experimental results demonstrated that suitable Rh loading (1 wt%) with appropriate reaction temperature (120 degrees C) and reaction time (8 h) were favorable for the formation of acetals, and a high acetals selectivity of 94.6% was achieved. More importantly, the selectivity to valuable linear products was enhanced in this tandem catalysis. Based on the catalytic mechanism study, highly dispersed RhOx nanoparticles and abundant acid sites on the supports were responsible for the hydroformylation and acetalization, respectively.
关键词	One-pot synthesis Tandem hydroformylation-acetalization Acetals Heterogenous catalyst
收录类别	SCI ; EI ; SCIE
资助项目	Ministry of Science and Technology of China[2017YFB0602202] ; Natural Science Foundation of China[91945301] ; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-SLH035]
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000604506700001
出版者	SPRINGER
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/124980
专题	物质科学与技术学院_特聘教授组_钟良枢组
通讯作者	Zhong, Liangshu
作者单位	1.Chinese Acad Sci, CAS Key Lab Low Carbon Convers Sci & Engn, Shanghai Adv Res Inst, Shanghai 201203, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201203, Peoples R China
通讯作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Li, Xiao,Qin, Tingting,Li, Liusha,et al. One-pot Synthesis of Acetals by Tandem Hydroformylation-acetalization of Olefins Using Heterogeneous Supported Catalysts[J]. CATALYSIS LETTERS,2021.
APA	Li, Xiao,Qin, Tingting,Li, Liusha,Wu, Bo,Lin, Tiejun,&Zhong, Liangshu.(2021).One-pot Synthesis of Acetals by Tandem Hydroformylation-acetalization of Olefins Using Heterogeneous Supported Catalysts.CATALYSIS LETTERS.
MLA	Li, Xiao,et al."One-pot Synthesis of Acetals by Tandem Hydroformylation-acetalization of Olefins Using Heterogeneous Supported Catalysts".CATALYSIS LETTERS (2021).