Toward a Deformable Two-Dimensional Covalent Organic Network with a Noncovalently Connected Skeleton

doi:10.1021/acs.chemmater.0c01344

	Toward a Deformable Two-Dimensional Covalent Organic Network with a Noncovalently Connected Skeleton
	Zhou, Xiao-He 1; Zheng, Si-Tai 1; Wang, Jian2 ; Wei, Lu 1; Fan, Yu 3; Liu, Li-Juan 1; Zhan, Tian-Guang 1; Cui, Jiecheng 1; Zhang, Kang-Da 1
	2020-10-13
发表期刊	CHEMISTRY OF MATERIALS (IF:7.2[JCR-2023],8.4[5-Year])
ISSN	0897-4756
卷号	32 期号:19 页码:8139-8145
发表状态	已发表
DOI	10.1021/acs.chemmater.0c01344
摘要	Exploring new structures of synthetic two-dimensional (2D) nanomaterials plays a crucial role in the development of such burgeoning materials toward more appealing functions and innovative potential applications. Herein, a new strategy is described to construct a unique 2D covalent organic network (CON) with a noncovalently connected skeleton through the facile solvothermal condensation of aromatic trialdehyde with a rationally designed unconventional macrocyclic diamine, which contains preorganized quadruple hydrogen-bonded ureidopyrimidinone (UPy) modules. The obtained UPy-integrated CON exhibits unique structural deformation behavior via the acid- base-induced de-/reformation of quadruple hydrogen bonds in the skeleton. This work enriches the structural tvues of the 2D nanomaterial by introducing a unique noncovalently preorganized building block; more promisingly, it develops a new strategy that offers unlimited opportunities in the design and construction of diverse synthetic CON materials concurrently featuring with structural regularity and deformability.
收录类别	SCI ; SCIE ; EI
语种	英语
资助项目	Natural Science Foundation of Zhejiang Province[LQ19B020006][LY20B020005]
WOS研究方向	Chemistry ; Materials Science
WOS类目	Chemistry, Physical ; Materials Science, Multidisciplinary
WOS记录号	WOS:000580949200008
出版者	AMER CHEMICAL SOC
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/123979
专题	生命科学与技术学院_公共科研平台_分子细胞学平台
通讯作者	Zhan, Tian-Guang; Zhang, Kang-Da
作者单位	1.Zhejiang Normal Univ, Coll Chem & Life Sci, Key Lab, Minist Educ Adv Catalysis Mat, Jinhua 321004, Zhejiang, Peoples R China 2.Shanghai Tech Univ, Sch Life Sci & Technol, Shanghai 201210, Peoples R China 3.Shanghai Univ, Coll Sci, Dept Phys, Shanghai 200444, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Xiao-He,Zheng, Si-Tai,Wang, Jian,et al. Toward a Deformable Two-Dimensional Covalent Organic Network with a Noncovalently Connected Skeleton[J]. CHEMISTRY OF MATERIALS,2020,32(19):8139-8145.
APA	Zhou, Xiao-He.,Zheng, Si-Tai.,Wang, Jian.,Wei, Lu.,Fan, Yu.,...&Zhang, Kang-Da.(2020).Toward a Deformable Two-Dimensional Covalent Organic Network with a Noncovalently Connected Skeleton.CHEMISTRY OF MATERIALS,32(19),8139-8145.
MLA	Zhou, Xiao-He,et al."Toward a Deformable Two-Dimensional Covalent Organic Network with a Noncovalently Connected Skeleton".CHEMISTRY OF MATERIALS 32.19(2020):8139-8145.