ShanghaiTech University Knowledge Management System
| Kinetic Resolution of 2-N-Acylamido Tertiary Allylic Alcohols: Asymmetric Synthesis of Oxazolines | |
| 2021-01-05 | |
| 发表期刊 | ADVANCED SYNTHESIS & CATALYSIS (IF:4.4[JCR-2023],4.6[5-Year]) |
| ISSN | 1615-4150 |
| 发表状态 | 已发表 |
| DOI | 10.1002/adsc.202001051 |
| 摘要 | A series of cyclohexyl-fused SPINOL-derived phosphoric acids (Cy-SPA) have been developed to catalyze the kinetic resolution of 2-N-acylamido tertiary allylic alcohols, providing access to chiral oxazolines bearing C-2 alkyl substituents with high enantioselectivities (with s-factors up to 153). Gram-scale reaction with 1 mol% catalyst loading and transformations of the chiral products demonstrates the value of these methods. |
| 关键词 | Asymmetric catalysis Organocatalysis Kinetic resolution Alcohols Oxazolines Novel spirocyclic phosphoric acids |
| 收录类别 | SCI ; SCIE ; IC ; CCR |
| 资助项目 | NSFC[21702138][21901162] ; Analytical Instrumentation Center[SPST-AIC10112914] |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Applied ; Chemistry, Organic |
| WOS记录号 | WOS:000584533500001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 引用统计 | 正在获取...
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| 文献类型 | 期刊论文 |
| 条目标识符 | https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/123969 |
| 专题 | 物质科学与技术学院_硕士生 物质科学与技术学院_PI研究组_杨晓瑜组 物质科学与技术学院_博士生 |
| 通讯作者 | He, Yu-Peng; Yang, Xiaoyu |
| 作者单位 | 1.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 2.Liaoning Shihua Univ, Key Lab Petrochem Catalyt Sci & Technol, Dandong Lu West 1, Fushun 113001, Peoples R China |
| 第一作者单位 | 物质科学与技术学院 |
| 通讯作者单位 | 物质科学与技术学院 |
| 第一作者的第一单位 | 物质科学与技术学院 |
| 推荐引用方式 GB/T 7714 | Pan, Yongkai,Jiang, Qianwen,Rajkumar, Subramani,et al. Kinetic Resolution of 2-N-Acylamido Tertiary Allylic Alcohols: Asymmetric Synthesis of Oxazolines[J]. ADVANCED SYNTHESIS & CATALYSIS,2021. |
| APA | Pan, Yongkai.,Jiang, Qianwen.,Rajkumar, Subramani.,Zhu, Chaofan.,Xie, Jinglei.,...&Yang, Xiaoyu.(2021).Kinetic Resolution of 2-N-Acylamido Tertiary Allylic Alcohols: Asymmetric Synthesis of Oxazolines.ADVANCED SYNTHESIS & CATALYSIS. |
| MLA | Pan, Yongkai,et al."Kinetic Resolution of 2-N-Acylamido Tertiary Allylic Alcohols: Asymmetric Synthesis of Oxazolines".ADVANCED SYNTHESIS & CATALYSIS (2021). |
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| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
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