Aminolysis of bis[bis(trimethylsilyl)amido]-manganese, -iron, and -cobalt for the synthesis of mono- and bis-silylene complexes

doi:10.1039/d0dt00570c

	Aminolysis of bis[bis(trimethylsilyl)amido]-manganese, -iron, and -cobalt for the synthesis of mono- and bis-silylene complexes
	He, Zhiyuan1,2,3 ; Xue, Xiaolian1 ; Liu, Yilan1 ; Yu, Na1 ; Krogman, Jeremy P.1
	2020-09-28
发表期刊	DALTON TRANSACTIONS (IF:3.5[JCR-2023],3.3[5-Year])
ISSN	1477-9226
卷号	49 期号:36 页码:12586-12591
发表状态	已发表
DOI	10.1039/d0dt00570c
摘要	We report a method for the synthesis of amidinate stabilized silylene (NHSi) metal-halide complexes from M{N(SiMe3)(2)}(2) (M = Mn, Fe, Co). The reported reactions can be used to make mono-silylene or bis-silylene complexes and the resulting products can be easily controlled by the reaction stoichiometry. Additionally, we apply this new synthetic protocol for the synthesis of a bis-iron complex derived from a bis-amidinate ligand having a terphenyl backbone.
收录类别	SCI ; SCIE ; EI
资助项目	National Natural Science Foundation of China[21801166]
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000571979900010
出版者	ROYAL SOC CHEMISTRY
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/123528
专题	物质科学与技术学院_硕士生物质科学与技术学院_PI研究组_jeremy krogman组物质科学与技术学院_公共科研平台_分析测试平台物质科学与技术学院_本科生
通讯作者	Krogman, Jeremy P.
作者单位	1.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China; 2.Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China; 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	He, Zhiyuan,Xue, Xiaolian,Liu, Yilan,et al. Aminolysis of bis[bis(trimethylsilyl)amido]-manganese, -iron, and -cobalt for the synthesis of mono- and bis-silylene complexes[J]. DALTON TRANSACTIONS,2020,49(36):12586-12591.
APA	He, Zhiyuan,Xue, Xiaolian,Liu, Yilan,Yu, Na,&Krogman, Jeremy P..(2020).Aminolysis of bis[bis(trimethylsilyl)amido]-manganese, -iron, and -cobalt for the synthesis of mono- and bis-silylene complexes.DALTON TRANSACTIONS,49(36),12586-12591.
MLA	He, Zhiyuan,et al."Aminolysis of bis[bis(trimethylsilyl)amido]-manganese, -iron, and -cobalt for the synthesis of mono- and bis-silylene complexes".DALTON TRANSACTIONS 49.36(2020):12586-12591.