苯丙素苷Acteoside, Isoacteoside和 Ligupurpuroside J的全合成
Hu Zhifei1,2; Xu Peng2; Wei Bingcheng2; Yu Biao1,2
2020-07-06
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
Volume41Issue:8Pages:1708-1720
Status已发表
DOI10.7503/cjcu20200266
Abstract

发展了一条合成苯丙素苷类化合物的通用路线,并依据此路线完成了苯丙素苷毛蕊花糖苷(Acteoside)和异毛蕊花糖苷(Isoacteoside)的全合成及紫茎女贞苷 J(Ligupurpuroside J)的首次全合成。其中的关键步骤是应用金(Ⅰ)催化的鼠李糖邻炔基苯甲酸酯给体与多羟基裸露的2-苯乙基葡萄糖苷进行区域选择性糖苷化反应,成功构建天然苯丙素苷中常见的α-(1→3)糖苷键。该合成路线减少了保护基的使用, 简洁高效。

Keyword苯丙素苷 毛蕊花糖苷 异毛蕊花糖苷 紫茎女贞苷J 糖苷化反应
MOST Discipline Catalogue理学::化学
Indexed BySCI
Language中文
Funding ProjectNational Natural Science Foundation of China[21621002]
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000563830700002
PublisherHIGHER EDUCATION PRESS
WOS KeywordGOLD(I)-CATALYZED GLYCOSYLATION ; ORTHO-ALKYNYLBENZOATES ; HEPATOPROTECTIVE ACTIVITY ; LEAVES ; CONSTITUENTS ; VERBASCOSIDE ; SAPONINS ; DONORS
Original Document TypeArticle
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttps://kms.shanghaitech.edu.cn/handle/2MSLDSTB/122769
Collection物质科学与技术学院_博士生
物质科学与技术学院_特聘教授组_俞飚组
Corresponding AuthorYu Biao
Affiliation1.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China
First Author AffilicationSchool of Physical Science and Technology
Corresponding Author AffilicationSchool of Physical Science and Technology
First Signature AffilicationSchool of Physical Science and Technology
Recommended Citation
GB/T 7714
Hu Zhifei,Xu Peng,Wei Bingcheng,等. 苯丙素苷Acteoside, Isoacteoside和 Ligupurpuroside J的全合成[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2020,41(8):1708-1720.
APA Hu Zhifei,Xu Peng,Wei Bingcheng,&Yu Biao.(2020).苯丙素苷Acteoside, Isoacteoside和 Ligupurpuroside J的全合成.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,41(8),1708-1720.
MLA Hu Zhifei,et al."苯丙素苷Acteoside, Isoacteoside和 Ligupurpuroside J的全合成".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 41.8(2020):1708-1720.
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