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Visible-light-promoted Dearomatization of Benzene and Derivatives
其他题名可见光促进的苯及衍生物去芳构化反应
2020-07-10
发表期刊高等学校化学学报 (IF:0.7[JCR-2023],0.5[5-Year])
ISSN0251-0790
卷号41期号:7页码:1407-1414
发表状态已发表
DOI10.7503/cjcu20200205
摘要

Benzene rings are widely found in petrochemicals, which are cheap and readily available. Compared with other (hetero)aromatic rings, the dearomatization of benzene rings is more challenging as benzene is more stable. On the other hand, visible-light photocatalysis has experienced rapid development since last decade. Upon visible-light irradiation, highly active intermediates are formed to break aromatic stability and to construct three-dimensional molecules from flat compounds. In this review, recent examples on visible-light-promoted dearomatization of benzene and derivatives are summarized, which can be divided into two main categories: ground-state chemistry and excited-state chemistry. The perspective for future development of this field is also discussed.
© 2020, Higher Education Press. All right reserved.

收录类别EI ; SCIE ; 北大核心 ; SCI
语种中文
资助项目National Natural Science Foundation of China[21821002] ; [18YF1428900]
出版者Higher Education Press
EI入藏号20202908945508
EI主题词Aromatization ; Benzene ; Excited states ; Ground state ; Quantum chemistry
EI分类号Light/Optics:741.1 ; Physical Chemistry:801.4 ; Chemical Reactions:802.2 ; Organic Compounds:804.1 ; Atomic and Molecular Physics:931.3
原始文献类型Journal article (JA)
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/121880
专题物质科学与技术学院_硕士生
物质科学与技术学院_特聘教授组_游书力组
通讯作者You, Shuli
作者单位
1.State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Shanghai; 200032, China
2.School of Physical Science and Technology, ShanghaiTech University, Shanghai; 201210, China
第一作者单位物质科学与技术学院
通讯作者单位物质科学与技术学院
推荐引用方式
GB/T 7714
Zhu, Min,Zhang, Xiao,You, Shuli. Visible-light-promoted Dearomatization of Benzene and Derivatives[J]. 高等学校化学学报,2020,41(7):1407-1414.
APA Zhu, Min,Zhang, Xiao,&You, Shuli.(2020).Visible-light-promoted Dearomatization of Benzene and Derivatives.高等学校化学学报,41(7),1407-1414.
MLA Zhu, Min,et al."Visible-light-promoted Dearomatization of Benzene and Derivatives".高等学校化学学报 41.7(2020):1407-1414.
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