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ShanghaiTech University Knowledge Management System
| Total Syntheses of Norrisolide-Type Spongian Diterpenes ChelovioleneC, SeconorrisolideB, and SeconorrisolideC | |
| 2020-08-10 | |
| 发表期刊 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (IF:16.1[JCR-2023],16.2[5-Year]) |
| ISSN | 1433-7851 |
| EISSN | 1521-3773 |
| 发表状态 | 已发表 |
| DOI | 10.1002/anie.202005600 |
| 摘要 | The first total syntheses of three unusual norrisolide-type rearranged spongian diterpenes, chelovioleneC, seconorrisolideB, and seconorrisolideC, have been accomplished via a common intermediate through late-stage ring-scissoring. The synthesis features a Wolff ring contraction for the synthesis of the trans-hydrindane system, and a crucial retro Diels-Alder reaction/intramolecular ene cyclization for the rapid stereoselective construction of the furo[2,3-b]furan system, which is commonly seen in rearranged spongian diterpenes. |
| 关键词 | cyclizations natural products rearrangements terpenoids total synthesis |
| 收录类别 | SCI ; SCIE ; EI ; IC |
| 语种 | 英语 |
| 资助项目 | National Key Research and Development Program of China[2017YFD0201404] ; National Natural Science Foundation of China[21971122][21772097][21572104] |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| WOS记录号 | WOS:000537512100001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS关键词 | ENE REACTION |
| 原始文献类型 | Article |
| 引用统计 | 正在获取...
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| 文献类型 | 期刊论文 |
| 条目标识符 | https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/121528 |
| 专题 | 物质科学与技术学院_PI研究组_梁广鑫组 |
| 通讯作者 | Liang, Guangxin |
| 作者单位 | 1.Nankai Univ, State Key Lab Elementoorgan Chem, Coll Chem, Tianjin 300071, Peoples R China 2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China |
| 通讯作者单位 | 物质科学与技术学院 |
| 推荐引用方式 GB/T 7714 | Qiao, Tianjiao,Wang, Yicheng,Zheng, Sujuan,et al. Total Syntheses of Norrisolide-Type Spongian Diterpenes ChelovioleneC, SeconorrisolideB, and SeconorrisolideC[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2020. |
| APA | Qiao, Tianjiao,Wang, Yicheng,Zheng, Sujuan,Kang, Huiying,&Liang, Guangxin.(2020).Total Syntheses of Norrisolide-Type Spongian Diterpenes ChelovioleneC, SeconorrisolideB, and SeconorrisolideC.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. |
| MLA | Qiao, Tianjiao,et al."Total Syntheses of Norrisolide-Type Spongian Diterpenes ChelovioleneC, SeconorrisolideB, and SeconorrisolideC".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020). |
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