Structure-related electrochemical performance of organosulfur compounds for lithium-sulfur batteries

doi:10.1039/c9ee03848e

	Structure-related electrochemical performance of organosulfur compounds for lithium-sulfur batteries
	Zhang, Xiaoyin1,2 ; Chen, Ke1,2 ; Sun, Zhenhua 1,3; Hu, Guangjian 1,3; Xiao, Ru 1,3; Cheng, Hui-Ming1,2,4 ; Li, Feng 1,3
	2020-04-01
发表期刊	ENERGY & ENVIRONMENTAL SCIENCE (IF:32.4[JCR-2023],34.5[5-Year])
ISSN	1754-5692
EISSN	1754-5706
卷号	13 期号:4 页码:1076-1095
发表状态	已发表
DOI	10.1039/c9ee03848e
摘要	Lithium-sulfur batteries (Li-S batteries) are promising next-generation energy storage devices due to their high theoretical energy density, low cost, and environmental compatibility. When trying to convert experiment into practice, one finds that sulfur cathodes, especially a cyclic octasulfur cathode, and lithium metal anodes present several problems, including sulfur shuttling, the fact that S is an insulator, complex 16-electron reactions, and the formation of lithium dendrites. In recent years, organosulfur compounds have been extensively investigated for Li-S batteries in order to solve these problems and understand the electrochemical process during their redox reactions. This review aims to summarize the different functions of organosulfur compounds, and figure out a guideline for understanding and using them in Li-S batteries. The organosulfur compounds currently used as active materials are classified into three types based on their electrochemical behavior, and design principles of the molecular and polymer structures of organosulfur compounds are concluded. Based on these design principles, we summarize how to control their electrochemical performance, and suggest possible electrochemical mechanisms and other characteristics. Finally, we propose guidelines for the development of promising organosulfur compounds using emerging technologies, including advanced characterization techniques, innovative methods of synthesis of such compounds, and machine-learning techniques.
收录类别	SCI ; SCIE ; EI
语种	英语
资助项目	Bureau of Industry and Information Technology of Shenzhen for the "2017 Graphene Manufacturing Innovation Center Project"[201901171523]
WOS研究方向	Chemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology
WOS类目	Chemistry, Multidisciplinary ; Energy & Fuels ; Engineering, Chemical ; Environmental Sciences
WOS记录号	WOS:000528728700001
出版者	ROYAL SOC CHEMISTRY
EI入藏号	20201808594340
EI主题词	Cathodes ; Learning systems ; Lithium batteries ; Lithium compounds ; Redox reactions ; Structural design ; Sulfur compounds
EI分类号	Structural Design, General:408.1 ; Primary Batteries:702.1.1 ; Chemical Reactions:802.2
WOS关键词	CATHODE MATERIALS ; HIGH-CAPACITY ; ELEMENTAL SULFUR ; INVERSE VULCANIZATION ; COMPOSITE CATHODE ; ENERGY ; COPOLYMERIZATION ; POLYSULFIDES ; CONFINEMENT ; POLYMERS
原始文献类型	Review
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/118927
专题	物质科学与技术学院_博士生物质科学与技术学院_特聘教授组_成会明组物质科学与技术学院_硕士生
通讯作者	Sun, Zhenhua; Li, Feng
作者单位	1.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China 2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei, Peoples R China 4.Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst, Shenzhen Geim Graphene Ctr, Shenzhen 518055, Peoples R China
第一作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Zhang, Xiaoyin,Chen, Ke,Sun, Zhenhua,et al. Structure-related electrochemical performance of organosulfur compounds for lithium-sulfur batteries[J]. ENERGY & ENVIRONMENTAL SCIENCE,2020,13(4):1076-1095.
APA	Zhang, Xiaoyin.,Chen, Ke.,Sun, Zhenhua.,Hu, Guangjian.,Xiao, Ru.,...&Li, Feng.(2020).Structure-related electrochemical performance of organosulfur compounds for lithium-sulfur batteries.ENERGY & ENVIRONMENTAL SCIENCE,13(4),1076-1095.
MLA	Zhang, Xiaoyin,et al."Structure-related electrochemical performance of organosulfur compounds for lithium-sulfur batteries".ENERGY & ENVIRONMENTAL SCIENCE 13.4(2020):1076-1095.