Transition-Metal-Free Electrophilic Fluoroalkanesulfinylation of Electron-Rich (Het)Arenes with Fluoroalkyl Heteroaryl Sulfones via C(Het)-S and S=O Bond Cleavage

doi:10.1002/adsc.201900959

	Transition-Metal-Free Electrophilic Fluoroalkanesulfinylation of Electron-Rich (Het)Arenes with Fluoroalkyl Heteroaryl Sulfones via C(Het)-S and S=O Bond Cleavage
	Wei, Jun 1; Bao, Kun 1; Qi, Chengcheng 1; Liu, Yao 1; Ni, Chuanfa 2; Sheng, Rong 1; Hu, Jinbo2,3
	2019-11-06
发表期刊	ADVANCED SYNTHESIS & CATALYSIS (IF:4.4[JCR-2023],4.6[5-Year])
ISSN	1615-4150
EISSN	1615-4169
发表状态	已发表
DOI	10.1002/adsc.201900959
摘要	A novel Ph2P(O)Cl-mediated direct fluoroalkanesulfinylation of electron-rich (het)arenes using fluoroalkyl heteroaryl sulfones as the RfSO source (R-f=C4F9, CF2Cl, CF2Br, and CF2COOEt) was developed. This is the first example where 2-HetSO(2)R(f) performs as the RfSO synthon in organic synthesis via both C(Het)-S and S=O bond cleavage.
关键词	fluoroalkanesulfinylation fluoroalkyl heteroaryl sulfones
收录类别	SCI ; SCIE ; IC ; CCR
语种	英语
资助项目	ZJNSF[LZ17H300002]
WOS研究方向	Chemistry
WOS类目	Chemistry, Applied ; Chemistry, Organic
WOS记录号	WOS:000494414200001
出版者	WILEY-V C H VERLAG GMBH
WOS关键词	DIFLUOROMETHYL 2-PYRIDYL SULFONE ; DIMETHYL-SULFOXIDE ; RADICAL FLUOROALKYLATION ; GEM-DIFLUOROOLEFINATION ; FLUORINATED SULFONES ; TRIFLUOROMETHYLATION ; ISOCYANIDES ; CHEMISTRY ; AROMATICS ; ALDEHYDES
原始文献类型	Article ; Early Access
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/102245
专题	物质科学与技术学院_特聘教授组_胡金波组
通讯作者	Sheng, Rong; Hu, Jinbo
作者单位	1.Zhejiang Univ, Coll Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R China 2.Chinese Acad Sci, Ctr Excellence Mol Synth, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Ling Ling Rd, Shanghai 200032, Peoples R China 3.ShanghaiTech Univ, Sch Phys Sci & Technol, 100 Haike Rd, Shanghai 201210, Peoples R China
通讯作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Wei, Jun,Bao, Kun,Qi, Chengcheng,et al. Transition-Metal-Free Electrophilic Fluoroalkanesulfinylation of Electron-Rich (Het)Arenes with Fluoroalkyl Heteroaryl Sulfones via C(Het)-S and S=O Bond Cleavage[J]. ADVANCED SYNTHESIS & CATALYSIS,2019.
APA	Wei, Jun.,Bao, Kun.,Qi, Chengcheng.,Liu, Yao.,Ni, Chuanfa.,...&Hu, Jinbo.(2019).Transition-Metal-Free Electrophilic Fluoroalkanesulfinylation of Electron-Rich (Het)Arenes with Fluoroalkyl Heteroaryl Sulfones via C(Het)-S and S=O Bond Cleavage.ADVANCED SYNTHESIS & CATALYSIS.
MLA	Wei, Jun,et al."Transition-Metal-Free Electrophilic Fluoroalkanesulfinylation of Electron-Rich (Het)Arenes with Fluoroalkyl Heteroaryl Sulfones via C(Het)-S and S=O Bond Cleavage".ADVANCED SYNTHESIS & CATALYSIS (2019).